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Name the reaction: R - OH + HCl to R -...

Name the reaction:
`R - OH + HCl to R - Cl + H_2O`

A

Swartz Reaction

B

Groove's Process

C

Darzen'sMethod

D

Peroxide effect

Text Solution

Verified by Experts

The correct Answer is:
B

Alcohol is mixed with hydrochloric acid and alkyl chloride is formed. Primary and secondary alcohol react with HCl in presence of anhyd. `ZnCl_2`. This process is known as Groove.s Process.
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Knowledge Check

  • Complete the reaction : R - OH + PCl_3 to R - Cl + ……………………

    A
    `H_3 PO_4 `
    B
    `POCl_3`
    C
    `H_3PO_3`
    D
    `HCl`
  • Name the reagent in the following reaction : R - OH + SOCl_2 to R - Cl + SO_2 uarr + HCl uarr

    A
    Pyridine
    B
    Heat
    C
    `C Cl_4`
    D
    None of these
  • What is the correct order of reactivity of alcohols in the following reaction ? R -OH +HCl rarr R-CI + H_2O

    A
    `1^(@) gt 2^(@) gt 3^@`
    B
    `1^(@) lt 2^(@) gt 3^@`
    C
    `3^(@) gt 2^(@) gt 1^@`
    D
    `3^(@) gt 1^(@) gt 2^@`
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