Home
Class 12
CHEMISTRY
Write Nernst equation and calculate e.m....

Write Nernst equation and calculate e.m.f. of the cell at 298 k.
`Mg(s)|Mg^(2+)(0.001 M)||Cu^(2+)(0.0001M)|Cu(s)`

Text Solution

Verified by Experts

At anode, `Mg rarr Mg^(2+) + 2e^(-)`
At cathode,
`ul(Cu^(2+) + 2e^(-) rarrCu)`
`ul(Mg+ Cu^(2+) rarr Mg^(2+) + Cu)`
`E= E^(@)- (0.059)/(2) "log" ([Mg^(2+)])/([Cu^(+)])`
`=2.71 - (0.059)/(2) "log" (0.01)/(0.0001)`
`=2.71- (0.059)/(2)`
=2.68V
Promotional Banner

Topper's Solved these Questions

  • ELECTRO CHEMISTRY

    ACCURATE PUBLICATION|Exercise 3 Marks each|15 Videos
  • D & F BLOCK ELEMENTS

    ACCURATE PUBLICATION|Exercise 2 OR 5 MARKS QUESTIONS|61 Videos
  • HALOALKANES AND HALOARENES

    ACCURATE PUBLICATION|Exercise TRUE AND FALSE (1 MARK)|10 Videos

Similar Questions

Explore conceptually related problems

Write Nernst equation and calculate e.m.f. of the following cell at 298 k. Mg(s)|Mg^(2+)(0.130M)||Ag^+(0.0001M)|Ag(s) Given E^o(Mg^(2+)//Mg)=-2.37 V E^o(Ag^(+)//Ag)=0.80 V (log 1.3=0.1130)

Write the Nernst equation and calculate e.m.f of following cell at 298K. Mg(s)|Mg^(2+)(0.130M)||Ag^(+)(0.0001M)|Ag(s) Given E_(Mg^(2+)//Mg)^(@)=-2.37V,E_(Ag^(+)//Ag)^(@)=0.80V . (log 1.3=0.1130)

Write the Nernst equation and emf of the following cells at 298 K: Mg(s)|Mg^(2+)(0.001M) || Cu^(2+)(0.0001 M)| Cu(s)

Write Nernst equation and calculate the e.m.f of the following cell at 298 K: Zn|Zn^(2+)(0.01M)||Fe^(2+)(0.005M)|Fe Given that: (Zn^(2+)//Zn)=-0.763V and E_(Fe^(2+)//Fe)^(@)=-0.44V" "log2=0.3010 .

Write Nernst equation and calculate the e.m.f. of the following cell at 298 K: Cu(s)|Cu^(2+)(0.130M)||Ag^(+)(1.0xx10^(-4)M)|Ag(s) Given that: E_(Cu^(2+)//Cu)^(@)=+0.34V and E_(Ag^(+)//Ag)^(@)=+0.80V (log 0.130=-1.1139).

Write the Nernst equation and calculate the emf of following cell at 298 K: Ni//Ni^(2+)(0.01M)||Cu^(2+)//Cu(0.01M) Given E^(@)(Cu^(2+)//Cu)=+0.34V,E^(@)(Ni^(2+)//Ni)=-0.025V

ACCURATE PUBLICATION-ELECTRO CHEMISTRY-Numbericals Practice
  1. Write Nernst equation and calculate e.m.f. of the cell at 298 k. Mg(...

    Text Solution

    |

  2. Write Nernst equation and calculate the e.m.f of the following cell at...

    Text Solution

    |

  3. Calculate the e.m.f. of the cell at 25^(@)C Cr|Cr^(3+)(0.1M)||Fe^(2+)(...

    Text Solution

    |

  4. Calculate the cell e.m.f. and DeltaG for the cell reaction at 25^(@)C ...

    Text Solution

    |

  5. State whether the statement is true or false- Lion is a herbivorous an...

    Text Solution

    |

  6. The calculate the e.mf. Of the following cell at 298: Fe|Fe^(2+)(0.1...

    Text Solution

    |

  7. Write Nernst equation and calculate e.m.f. of the cell at 298 k. Mg(...

    Text Solution

    |

  8. Write the Nernst equation and calculate the e.m.f. of the following ce...

    Text Solution

    |

  9. Write The Nernst equation and calculate the e.m.f. of the following ce...

    Text Solution

    |

  10. Calculate the cell e.m.f. and DeltaG for the cell reaction at 25^(@)C ...

    Text Solution

    |

  11. Calculate DeltaG and E(cell) for the cell: AI//AI^(3+)(0.01M)||Fe^(2...

    Text Solution

    |

  12. The resistance of 0.5N solution of an electrolyte ina conductivity cel...

    Text Solution

    |

  13. Write Nernst equation and calculate the e.m.f of the following cell at...

    Text Solution

    |

  14. The calculate the e.mf. Of the following cell at 298: Fe|Fe^(2+)(0.1...

    Text Solution

    |

  15. Calculate the e.m.f. of the cell at 25^(@)C Cr|Cr^(3+)(0.1M)||Fe^(2+)(...

    Text Solution

    |

  16. Write Nernst equation and find e.m.f of cell Ni//Ni((0.01M))^(2+)//Cu(...

    Text Solution

    |

  17. Write Nernst equation and calculate e.m.f. of the cell at 298 k. Mg(...

    Text Solution

    |

  18. Write Nernst equation and calculate the e.m.f. of the following cell a...

    Text Solution

    |

  19. Calculate the cell e.m.f for reaction. Zn((s))//Zn((0.0004M))^(2+)//C...

    Text Solution

    |

  20. Calculate DeltaG and E(cell) for the cell: AI//AI^(3+)(0.01M)||Fe^(2...

    Text Solution

    |