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Calculate DeltaG and E(cell) for the cel...

Calculate `DeltaG and E_(cell)` for the cell:
`AI//AI^(3+)(0.01M)||Fe^(2+)(0.02M)//Fe` given that `E^(@)(Al^(3+)//Al)=-1.66V and E^(@)(Fe^(2+)//Fe)=-0.44V`

Text Solution

Verified by Experts

At anode, `2Al rarr 2Al^(3+) + 6e^(-)`
At cathode,
`ul(3Fe^(2+) +6e^(-) rarr 3Fe)`
`ul(2Al+ 3Fe^(2+) rarr 2Al^(3+) + 3Fe)`
`E= E^(@)- (0.059)/(2) "log" ([Al^(3-)]^(2))/([Fe^(2+)]^(3))`
`=1.22 - (0.059)/(2)"log" ((0.01)^(2))/((0.02)^(3))`
=1.209V
`Delta G^(@)= -nEF`
`=6(1.209) (065001)`
`=-700011J mol^(-1)`
`=-700.011k J mol^(-1)`
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ACCURATE PUBLICATION-ELECTRO CHEMISTRY-Numbericals Practice
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  2. Write Nernst equation and calculate the e.m.f of the following cell at...

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  3. Calculate the e.m.f. of the cell at 25^(@)C Cr|Cr^(3+)(0.1M)||Fe^(2+)(...

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  4. Calculate the cell e.m.f. and DeltaG for the cell reaction at 25^(@)C ...

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  6. The calculate the e.mf. Of the following cell at 298: Fe|Fe^(2+)(0.1...

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  7. Write Nernst equation and calculate e.m.f. of the cell at 298 k. Mg(...

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  8. Write the Nernst equation and calculate the e.m.f. of the following ce...

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  9. Write The Nernst equation and calculate the e.m.f. of the following ce...

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  10. Calculate the cell e.m.f. and DeltaG for the cell reaction at 25^(@)C ...

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  11. Calculate DeltaG and E(cell) for the cell: AI//AI^(3+)(0.01M)||Fe^(2...

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  13. Write Nernst equation and calculate the e.m.f of the following cell at...

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  14. The calculate the e.mf. Of the following cell at 298: Fe|Fe^(2+)(0.1...

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  15. Calculate the e.m.f. of the cell at 25^(@)C Cr|Cr^(3+)(0.1M)||Fe^(2+)(...

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  17. Write Nernst equation and calculate e.m.f. of the cell at 298 k. Mg(...

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  18. Write Nernst equation and calculate the e.m.f. of the following cell a...

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  19. Calculate the cell e.m.f for reaction. Zn((s))//Zn((0.0004M))^(2+)//C...

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  20. Calculate DeltaG and E(cell) for the cell: AI//AI^(3+)(0.01M)||Fe^(2...

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