Home
Class 12
CHEMISTRY
Find the half life time period for first...

Find the half life time period for first order reaction.

Text Solution

Verified by Experts

The first order rate equation for reaction
`kt = 2.303 "log" ([A]_0)/([A])`
`t = (2.303)/k "log"([A]_0)/([A])`
half life time means that concentration decrease to half if its initial concentration
`[A] = ([A]_0)/(2) " and " t = (t_(1/2))`
`t_(1/2) = (2.303)/(k) "log" ([A]_0)/([A]_0) 2`
`t_(1/2) = (2.303)/(k) xx log 2 " " [log 2 = 0.3010]`
`t_(1/2) = (2.303)/(k) xx 0.3010`
`t_(1/2) = (0.693)/(k)`
It shows that half life period of a first order reaction independent of Initial concentration of its reactant.
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    ACCURATE PUBLICATION|Exercise NUMERICAL OF HALF LIFE TIME PERIOD |6 Videos
  • CHEMICAL KINETICS

    ACCURATE PUBLICATION|Exercise ARRHENIUS EQUATIONS |11 Videos
  • CHEMICAL KINETICS

    ACCURATE PUBLICATION|Exercise 1 MARK QUESTIONS|24 Videos
  • BOARD PAPER MARCH - 2020

    ACCURATE PUBLICATION|Exercise SECTION - D|18 Videos
  • COORDINATION COMPOUNDS

    ACCURATE PUBLICATION|Exercise 2 MARKS QUESTIONS|23 Videos

Similar Questions

Explore conceptually related problems

Find the half life period of first order reaction whose rate constant, k=4.93xx 10^-4 s^-1 .

Average life time is more/less than half life time for a first order reaction.

True or False : The half life Period for a first order reaction is independent of its initial Concentration.

If the half life period of a first order reaction is 100 seconds, then rate constant will be

Calculate the half life period of a first order reaction whose specific rate constant is 5.5 xx 10^(-14) s