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Write short note on Hoffmann's bromamide...

Write short note on Hoffmann's bromamide reaction. Why is it regarded as Hoffmann degradation reaction?

Text Solution

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This reaction involves the heating of an amide with bromine and caustic alkali to yield an amine with one carbon less than the original amide.
`underset("Amide")(RCONH_2)+Br_2+4KOHrarrunderset("Amide")(R-NH_2)+K_2CO_3+2KBr+2H_2O`
This is also known as Hoffmann bromamida degradations because the amine formed has one carbon atom less than the number of carbon atoms in the example
For example:
`underset("Ethyl Amide")(C_2H_5CONH_2)+Br_2+4KOHrarrunderset("Ethyl Amide")(C_2H_5NH_2)+K_2CO_3+2KBr+2H_2O`
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