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Why are the boiling points of carboxylic...

Why are the boiling points of carboxylic acids higher than the corresponding alcohols ?

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We know that, carboxylic acids and alcoliols both have intermolecular hydrogen bonding in their molecules. But O-H bond in carboxylic acids is more polarised than in alcohols due to the presence of > C = 0 group. hence, the magnitude of hydrogen bonding in acids is more than that in alcohols, i.e. hydrogen bonds are stronger in acids.
Also, exists as dimer. It increases degree of hydrogen bonding and hence higher will be the boiling point of acids :

Aliphatic carboxylic acids having carbon atom up to four are soluble in water. But solubility of acids decreases with increases of carbon atom. This is due to increased, hydrophobic interactions of hydrocarbons.
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ACCURATE PUBLICATION-ALDEHYDES ,KETONES AND CARBOOXALIC ACIDS-CARBOXYLIC ACID (3 MARK QUESTIONS )
  1. The symbol of the elements cobalt , aluminium , helium and sodium resp...

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  2. Carboxylic acid exists as dimers, explain why ?

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  3. Why are the boiling points of carboxylic acids higher than the corresp...

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  4. Carboxylic acids do not give the characteristic reactions of carbonyl ...

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  5. Benzoic acid is stronger acid than acetic acid. Justify.

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  6. Fluoroacetic acid is stronger than chloroacetic acid. Explain why ?

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  7. Why carboxylic acids do not give characteristic reactions of -OH group...

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  8. How will you account for the acidic nature of carboxylic acid ?

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  9. Benzoic acid is stronger acid than acetic acid. Justify.

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  10. How will you account for the acidic nature of carboxylic acid ?

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  11. Why acetic acid is weaker than formic acid ?

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  12. Why chloroacetic acid is stronger acid than acetic acid ?

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  13. Benzoic acid is stronger acid than acetic acid. Justify.

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  14. Why trichloro acetic acid is stronger than acetic acid ?

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  15. Chloroacetic acid has lower pK(alpha) value than acetic acid. Explain,

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  16. Why dichloroacetic acid is stronger than monochloroacetic acid ?

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  17. Carboxylic acid exists as dimers, explain why ?

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  18. Most aromatic acids are solids while acetic acid and others of their s...

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  19. Formic acid is stronger acid than acetic acid. Justify.

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  20. Benzoic acid is stronger acid than acetic acid. Justify.

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