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How will you account for the acidic natu...

How will you account for the acidic nature of carboxylic acid ?

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Acidic nature of carboxylic acids and phenols : Both acids and phenols are resonance stabilised. They release `H^+` ions easily to form carboxylate ions and phonoxide ions respectively as :

Resonance hybrid of phenoxide ion is :

In the hybrid of carboxylate ion, the negative charge is dispersed on two oxygen atoms and there is one oxygen atom to disperse negative charge in phenoxide ion. So, dispersal of negative charge is more on carboxylate ion than phenoxide ion. Ilence carboxylate ions are more stable than phenoxide ions. It leads to the conclusion that carboxylic acids are more acidic than phenols.
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ACCURATE PUBLICATION-ALDEHYDES ,KETONES AND CARBOOXALIC ACIDS-CARBOXYLIC ACID (3 MARK QUESTIONS )
  1. Why are the boiling points of carboxylic acids higher than the corresp...

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  2. Carboxylic acids do not give the characteristic reactions of carbonyl ...

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  3. Benzoic acid is stronger acid than acetic acid. Justify.

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  4. Fluoroacetic acid is stronger than chloroacetic acid. Explain why ?

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  5. Why carboxylic acids do not give characteristic reactions of -OH group...

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  6. How will you account for the acidic nature of carboxylic acid ?

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  7. Benzoic acid is stronger acid than acetic acid. Justify.

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  8. How will you account for the acidic nature of carboxylic acid ?

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  9. Why acetic acid is weaker than formic acid ?

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  10. Why chloroacetic acid is stronger acid than acetic acid ?

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  11. Benzoic acid is stronger acid than acetic acid. Justify.

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  12. Why trichloro acetic acid is stronger than acetic acid ?

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  13. Chloroacetic acid has lower pK(alpha) value than acetic acid. Explain,

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  14. Why dichloroacetic acid is stronger than monochloroacetic acid ?

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  15. Carboxylic acid exists as dimers, explain why ?

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  16. Most aromatic acids are solids while acetic acid and others of their s...

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  17. Formic acid is stronger acid than acetic acid. Justify.

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  18. Benzoic acid is stronger acid than acetic acid. Justify.

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  19. p-Nitrobenzoic acid is a stronger acid than benzoic acid. Justify.

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  20. Aldehyde are more reactive than ketone ?Explain why.

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