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Which of the following compounds does no...

Which of the following compounds does not react with `NaNO_2 ` and HCI ?

A

`C_6H_5OH`

B

`C_6H_5NH_2`

C

`(CH_3)_3CNO_2`

D

`(CH_3)_2CHNO_2`

Text Solution

Verified by Experts

The correct Answer is:
C
With nitrous acid : (i) phenol gives p-nitrosophenol, (ii) aniline gives diazonium salt, and (iii) `2^@` nitro compounds givepseudonitrole, while `3^@` nitro compounds do not react because they have no a-hydrogen atom .
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ACCURATE PUBLICATION-ORGANIC COMPOUNDS CONTAINING NITROGEN COMPOUNDS-MULTIPLE CHOICE QUESTIONS
  1. The reagent that reacts with nitro methane to form methyl hydroxylamin...

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  2. Nitrobenzene on electrolytic reduction in strongly acidic medium gives

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  3. Which of the following compounds does not react with NaNO2 and HCI ?

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  4. The reaction of HCOOH with conc. H 2 S O 4 gives

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  5. Which of the following compound is not explosive?

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  6. which of the following food items contain protein? Milk, groundnut, ve...

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  7. Treatment of ammonia with excess of ethyl iodide will yield: Diethyl...

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  8. Butane nitrile may be prepared by heating

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  9. Which of the following gives primary amine on reduction ?

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  10. Intermediates formed during reaction of RCONH2 with Br2 and KOH are

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  11. Gabriel phthalimide reaction is used for the prepration of

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  12. Which of the following reactions will not give a primary amine?

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  13. On reduction, secondary amine is given by

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  14. Which is formed when (CH3)4 NOH is heated ?

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  15. The one which is least basic is

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  16. Which one of the following is more basic?

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  17. Which of the following-statement is not correct?

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  18. The correct order of increasing basicity in aqueous solution is

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  19. The amine that does not react with acetyl chloride is

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  20. Aniline on reaction with acetyl chloride gives

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