Home
Class 12
CHEMISTRY
R-COOHtoR-CH(2)OH. This mode of reductio...

`R-COOHtoR-CH_(2)OH`. This mode of reduction of an
acid to alcohol can be effected by :

A

`Zn//HCl`

B

Na-alcohol

C

Aluminium isopropoxide and isopropyl alcohol

D

`LiAlH_(4)`

Text Solution

AI Generated Solution

The correct Answer is:
To convert a carboxylic acid (R-COOH) to a primary alcohol (R-CH2OH), we can use specific reducing agents. Here’s a step-by-step solution: ### Step 1: Identify the Reactants and Products - **Reactant**: R-COOH (Carboxylic acid) - **Product**: R-CH2OH (Primary alcohol) ### Step 2: Determine the Type of Reaction - This is a reduction reaction where the carboxylic acid is being reduced to a primary alcohol. ### Step 3: Select the Appropriate Reducing Agent - The most suitable reducing agents for this conversion are: - **Lithium Aluminium Hydride (LiAlH4)**: This is a strong reducing agent capable of reducing carboxylic acids to alcohols. - **Diborane (B2H6)**: This is another reducing agent that can also achieve the same conversion. ### Step 4: Write the Reaction - The reduction can be represented as follows: \[ \text{R-COOH} + \text{LiAlH}_4 \rightarrow \text{R-CH}_2\text{OH} \] or \[ \text{R-COOH} + \text{B}_2\text{H}_6 \rightarrow \text{R-CH}_2\text{OH} \] ### Step 5: Conditions for the Reaction - The reaction typically requires the presence of an ether solvent to stabilize the reducing agent during the reaction process. - After the reduction, an acid work-up (like H3O+) is often used to protonate the alkoxide intermediate formed during the reduction. ### Final Answer The mode of reduction of an acid (R-COOH) to an alcohol (R-CH2OH) can be effectively achieved using **Lithium Aluminium Hydride (LiAlH4)** or **Diborane (B2H6)**. ---

To convert a carboxylic acid (R-COOH) to a primary alcohol (R-CH2OH), we can use specific reducing agents. Here’s a step-by-step solution: ### Step 1: Identify the Reactants and Products - **Reactant**: R-COOH (Carboxylic acid) - **Product**: R-CH2OH (Primary alcohol) ### Step 2: Determine the Type of Reaction - This is a reduction reaction where the carboxylic acid is being reduced to a primary alcohol. ...
Promotional Banner

Similar Questions

Explore conceptually related problems

Reduction of gtC=O to CH_(2) can be carried out with

Of the two alcohols, (a) CH_(2)=CH-CH_(2)OH and (b) CH_(2)=CH-CH_(2)-CH_(2)OH , which one will react more easily with conc. HCl in the presence of ZnCl_(2) ?

CH_(3)CH_(2)CH(OH)CH(CH_(3))_(2)+CH_(3)COCI overset("base")rarr CH_(3)CH_(2)CH(OCOCH_(3))CH(CH_(3))_(2)+HCI In the above reaction, if the reactant alcohol is a pure R-isomer the product would.

A 5.2 molal aqueous of methyl alcohol, CH_(3)OH , is supplied. What is the molefraction of methyl alcohol in the solution ?

Which of the following statements are correct about the following reaction : R-overset(O)overset(||)(C)-OH+R'OHoverset(H^(o+))hArrRCOOR'+H_(2)O (a)Rate = K[RCOOH][R' OH][H^(+)] . First order in acid, alcohol, and H^(oplus) , third order overall. (b)Rate : K[RCOOH][R' OH] . First order in acid and alcohol , second order overall. (c)Slow and rate-determining step (R.D.S) is the addition of alcohol to the protonated acid. (d)Slow and rate-determining step (R.D.S) is the addition of acid to the protonated alcohol.