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CH(3)CH=CH(2)underset(H(2)O(2)//OH)overs...

`CH_(3)CH=CH_(2)underset(H_(2)O_(2)//OH)overset(NaBD_(4))to` Product X, X is :

A

`CH_(3)underset(OH)underset(|)(C)HCH_(2)D`

B

`CH_(3)underset(D)underset(|)(C)HCH_(2)OH`

C

`CH_(3)underset(OD)underset(|)(C)HCH_(3)`

D

none is correct

Text Solution

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The correct Answer is:
To solve the question, we need to determine the product formed when 1-propene (CH3CH=CH2) reacts with NaBD4 in the presence of H2O2 and OH-. ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactant is 1-propene (CH3CH=CH2). This is an alkene with a double bond between the second and third carbon atoms. **Hint**: Look for the functional groups and the structure of the reactant. 2. **Identify the Reagents**: The reagents are NaBD4 (sodium borodeuteride), H2O2 (hydrogen peroxide), and OH- (hydroxide ion). NaBD4 is a reducing agent that will facilitate the reduction of the alkene. **Hint**: Recognize the role of each reagent in the reaction. 3. **Understand the Reaction Mechanism**: The reaction involves the reduction of the alkene. NaBD4 will add deuterium (D) across the double bond. The presence of H2O2 and OH- suggests that the addition will follow the anti-Markovnikov rule, meaning that the -D will add to the less substituted carbon. **Hint**: Recall the concept of Markovnikov's rule and its opposite, anti-Markovnikov's rule. 4. **Break the Double Bond**: The double bond in 1-propene will break, and the -D will add to the terminal carbon (the less substituted carbon), while -OH will add to the more substituted carbon. **Hint**: Visualize the breaking of the double bond and the addition of new groups. 5. **Draw the Product**: After the addition, the structure of the product will be: - The carbon that was part of the double bond will now have a -D and a -OH group attached. - The product can be represented as CH3-CH(D)-CH2(OH). **Hint**: Ensure that you correctly place the -D and -OH groups according to the anti-Markovnikov addition. 6. **Final Product Structure**: The final product can be written as CH3-CH(D)-CH2OH. This indicates that we have a secondary alcohol with deuterium at the second carbon. **Hint**: Confirm that the product reflects the correct addition pattern and that all valencies are satisfied. ### Conclusion: The product X formed from the reaction of CH3CH=CH2 with NaBD4 in the presence of H2O2 and OH- is **CH3-CH(D)-CH2OH**.

To solve the question, we need to determine the product formed when 1-propene (CH3CH=CH2) reacts with NaBD4 in the presence of H2O2 and OH-. ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactant is 1-propene (CH3CH=CH2). This is an alkene with a double bond between the second and third carbon atoms. **Hint**: Look for the functional groups and the structure of the reactant. ...
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