Home
Class 11
CHEMISTRY
The hybridization of N atoms in NO3^(-),...

The hybridization of N atoms in `NO_3^(-), NO_2^(+)` and `NH_4^(+)` are respectively:

A

`sp^2, sp, sp^3`

B

`sp, sp^3, sp^2`

C

`sp^2, sp^3, sp`

D

`sp, sp^2, sp^3`

Text Solution

Verified by Experts

The correct Answer is:
A

The expression can be written as ` H = 1/2 [V + M - c + a]`
where V is the number of valence electrons around central atom, M is the number of monovalent groups attached, c is the charge on cation and a is the charge on anion.
`NO_3^- :H = 1/2 [5+0-0+1] =3, NO_2^+ : H = 1/2 [5+0-1+0] = 2,NH_4^+ : H = 1/1 [5+4-1+0]=4 `
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL BONDING

    BRILLIANT PUBLICATION|Exercise LEVEL-II (ASSERTION-REASON TYPE)|20 Videos
  • CHEMICAL BONDING

    BRILLIANT PUBLICATION|Exercise QUESTIONS|6 Videos
  • CHEMICAL BONDING

    BRILLIANT PUBLICATION|Exercise LEVEL-I|120 Videos
  • CHEMICAL AND IONIC EQUILIBRIUM

    BRILLIANT PUBLICATION|Exercise Level - III (Linked Comprehension Type Questions)|1 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    BRILLIANT PUBLICATION|Exercise QUESTION (LEVEL -ll)|42 Videos

Similar Questions

Explore conceptually related problems

The hybridisation of atomic orbitals of nitrogen in NO2+, NO3- and NH4+are 1. sp, sp and sp respectively 2.sp, sp2 and sp3 respectively 3.sp2, sp and sp3 respectively 4.sp2, sp3 and sp respectively.

The gases produced in the reactions Pb(NO3)2 -> Δ and 'NH4NO3' -> Δ are respectively,

Delta H _(f) ^(0) values of NH _(2) - OH _((s)), NH _(3 (g)), N _(2) H _(4 (l)) and NH _(4) NO _(3 (s)) are respectively (in kJ mol^(-1) ) -114, 294, 50.6 and -365.5. The order of increasing stability with respect to decomposition into their elements is.

Calculate the oxidation number of N in NO_3^- .

Specify the hybridisation of the central atom in the following species respectively N_(3) ^(-), NOCl , N_(2)O

BRILLIANT PUBLICATION-CHEMICAL BONDING-LEVEL-II
  1. The bond order in NO is 2.5 whereas that in NO^(+) is 3. Which of the ...

    Text Solution

    |

  2. Which of the following molecules has the greatest number of lone pairs...

    Text Solution

    |

  3. The hybridization of N atoms in NO3^(-), NO2^(+) and NH4^(+) are respe...

    Text Solution

    |

  4. The number and type of bonds in C2^(2-) ion in CaC2 are:

    Text Solution

    |

  5. Shapes of certain interhalogen compounds are stated below. Which one o...

    Text Solution

    |

  6. In which of the following chemical change, the hybridization of the ce...

    Text Solution

    |

  7. In which of the following ionization processes, the bond order has inc...

    Text Solution

    |

  8. The bond dissociation energy of B-F in BF3 is 646 kJ mol^(-1), whereas...

    Text Solution

    |

  9. Among the following the paramagnetic compound is

    Text Solution

    |

  10. The bond energy (in kJ mol^(-1)) of C-C single bond is, approximately,

    Text Solution

    |

  11. Assuming that Hund's rule is violated, the bond order and magnetic nat...

    Text Solution

    |

  12. According MO theory, : O2^(+) is paramagnetic and bond order greate...

    Text Solution

    |

  13. The species having bond order different from that in CO is

    Text Solution

    |

  14. The "charge"//"size" ratio of a cation determines its polarizing power...

    Text Solution

    |

  15. In which of the following pairs , the two species are not isostructura...

    Text Solution

    |

  16. Which of the following isnot correct regarding C2 molecule? : C2 mol...

    Text Solution

    |

  17. Hybridization, shape and number of pi bonds in XeOF2 molecule are, res...

    Text Solution

    |

  18. Which of the following pairs of atoms combine to give non directional ...

    Text Solution

    |

  19. Which one of the following molecules has the largest dipole moment? (E...

    Text Solution

    |

  20. Which of the following molecules form no intermolecular hydrogen bonds...

    Text Solution

    |