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The percent ionic character of a polar b...

The percent ionic character of a polar bond may be computed from the expression Percent ionic character = `(P_("observed"))/(P_("ionic")) xx 100` where P stands for dipole moment.
Based on the values of percent ionic character computed by the above expression, Pauling obtained t expression, percent ionic character = `18 (chi_x - xhi_H)^(1.4)`
where `Chi_x ` and `chi_H` are electronegativity values of a halogen atom and H, respectively.
The variation of percent ionic character and electronegativity difference for H-X(where X is halogen) is shown in Figure:

A

B

C

D

Text Solution

Verified by Experts

The correct Answer is:
B

Percent ionic character decreases sharply with decrease in electronegativity of halogens, the decrease is less sharp among heavier members.
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