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When I^(-) is oxidised by MnO(4)^(-) in ...

When `I^(-)` is oxidised by `MnO_(4)^(-)` in alkaline medium, `I^(-)` converts into

A

`IO_(3)^(-)`

B

`I_2`

C

`IO_(4)^(-)`

D

` IO^(-)`

Text Solution

Verified by Experts

The correct Answer is:
A

A The reaction involved is ` 2 MnO_(4)^(-) +H_2 O +I^(-) to 2 MnO_2 + 2OH^(-) + IO_(3)^(-)`
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Calculate the equivalent weight of the following: (i) KMnO_4 in acidic medium (ii) KMnO_4 in alkaline medium (iii) FeSO_4 (NH_4)_2 SO_4. 6H_(2) O (converting to Fe^(3+) ) (iv) K_2 Cr_2 O_7 in acidic medium (v) H_2 C_2 O_4 (converting to CO_2 ) (vi) Na_(2) S_(2) O_(3). 5H_(2) O ( reacting with I_2 )

MnO_(4)^(-) is reduced to Mn^(2+) in acidic medium and to MnO_(2) in neutral medium when MnO_(4)^(-) acts as oxidant 20 ml of a solution of Fe^(2+) required 30 ml MnO_(4)^(-) solution in acidic medium. What volume of this aq MnO_(4)^(-) is needed for the same Fe^(2+) solution if 30 ml is used in neutral medium

The highest pH value in the alkaline medium.

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