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o-Toluic acid on reaction with Br(2)+Fe ...

o-Toluic acid on reaction with `Br_(2)+Fe` gives

A

B

C

D

Text Solution

Verified by Experts

The correct Answer is:
C

`CH_(3)` is o, p-directing and COOH is m-directing. Both these effects reinforce each other and hence substitution occurs at position p-to `CH_(3)` and m-to COOH group, ie, option (C ) is correct.
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BRILLIANT PUBLICATION-CARBOXYLIC ACID & THEIR DERIVATIVES-LEVEL-II
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  2. Which of the following acids on heating loses a molecule of H(2)O to f...

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  3. o-Toluic acid on reaction with Br(2)+Fe gives

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  4. Which of the following produces benzoic acid?

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  6. Maleic acid and fumaric acid are two unsaturated dicarboxylic acids. W...

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  7. In which of the following reactions, the number of carbon atoms does n...

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  8. In a set of reactions, acetic acid gives the following product 'D'CH(3...

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  9. (A), (B) and (C ) are three dicarboxylic acids such that: (A) overse...

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  10. HCOOH overset("Conc."H(2)SO(4))to X+Y. Products X and Y are respective...

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  11. CH(3)CO(2)C(2)H(5) on reaction with sodium ethoxide in ethanol gives (...

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  12. End product of this conversion CH(3)-overset(O)overset(||)C-CH(2)-CH(2...

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  13. When acetic acid reacts with ketene, product formed is:

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  14. Which of the following compound would be expected to decarboxylate whe...

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  15. , A is ?

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  16. End product of the following sequence of reaction is:

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  17. On subjecting mesityl oxide to the iodoform reaction, one of the produ...

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  18. The ease of alkaline hydrolysis is more for:

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  19. Which of the following does not form benzoic acid on oxidation with KM...

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  20. p-Nitrobenzoic acid is a stronger acid than benzoic acid. This is due ...

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