Home
Class 12
CHEMISTRY
A solid has a b.c.c. structure. If the d...

A solid has a b.c.c. structure. If the distance of closest approach between the two atoms is 1.73Å. The edge length of the cell is:

A

200 pm

B

`(sqrt(3))/(sqrt(2))`pm

C

142.2 pm

D

`sqrt(2)` pm

Text Solution

Verified by Experts

The correct Answer is:
A

`r_("atom")=(sqrt(3))/(4)a`, also closest approach in bcc lattice is `1/2` of body diagonal.
i.e., `(sqrt(3))/(2)a=1.73Å` or `a=(1.73xx2)/(sqrt3)=1.996`Å=199.6 pm
Promotional Banner

Topper's Solved these Questions

  • SOLID STATE

    BRILLIANT PUBLICATION|Exercise LEVEL-3|10 Videos
  • SOLID STATE

    BRILLIANT PUBLICATION|Exercise LEVEL-3 (Multiple Correct Answer Type)|13 Videos
  • SOLID STATE

    BRILLIANT PUBLICATION|Exercise LEVEL-1|50 Videos
  • REDOX REACTION & ELECTROCHEMISTRY

    BRILLIANT PUBLICATION|Exercise QUESTION (ELECTROCHEMISTRY) (LEVEL -II) (ASSERTION-REASON)|3 Videos
  • SOLUTIONS

    BRILLIANT PUBLICATION|Exercise Level-III (Linked Comprehension Type)|12 Videos

Similar Questions

Explore conceptually related problems

Assertion (A) : In Rock salt type structuires, all the coctahedral voids in the close packing of anions are occupied by cations. Reason(R): In Rock salt structure, the distance of closest apprach between two anions is equal to hal the face diagonal of unit cell.

A crystalline solid has simple cubic structure in which P atoms are present at the corners, Q atoms are present at the edge centres and R atoms are present at the centre of the unit cell. What is the formula of the compound?

A crystalline solid has a cubic structure In which Tungsten (W) atoms are located at the cubic comers of the unit cell, oxygen atoms at the cube edges and sodium atom at the cube centre. What is the molecular formula of the compound?

A solid has a cubic structure in which 'X' atoms are located at the C0rners of the cube, 'Y' atoms are at the cube centres and 0 atoms are at the edge centres. What is the formula of the compound?

A solid has a structure in which W atoms are located at the C0rners of a lattice, O atoms at the centre of the edges and Na atom at the centre of the cube. The formula of the compound is

A solid has cubic structure in which X atoms are located at the corners of the cube, Y atoms at the body centre and O atoms at the edge centres. What is the formula of the compound?

Density of a unit cell is the same as the density of the substance. So, if the density of the substance is known, we can calculate the number of atoms or dimensions of the unit cell. The density of the unit cell is related to its formula mass (M), number of atoms per unit cell (z), edge length (a in cm), and Avogadro's constant N_(A) , as rho=(zxxM)/(a^(3)xxN_(A)) Q. A metal A (atomic mass=60) has a body-centred cubic crystal structure. the density of the metal is 4.2 g cm^(-3) . the volume of unit cell is

BRILLIANT PUBLICATION-SOLID STATE-LEVEL-2
  1. If 'a' stands for the edge length of the cubic systems: simple cubic, ...

    Text Solution

    |

  2. The density of KBr is 2.75 gm cm^(-3) and length of the unit cell is 6...

    Text Solution

    |

  3. A solid has a b.c.c. structure. If the distance of closest approach be...

    Text Solution

    |

  4. Experimentally it was found that a metal oxide has formula M(0.98)O. M...

    Text Solution

    |

  5. In a close packed face-centred unit cell, are all lattice positions oc...

    Text Solution

    |

  6. Element X crystallizes in a 12 co-ordination fcc lattice. On applying ...

    Text Solution

    |

  7. When a crystal surface is exposed to X-rays of 250 pm wave length, the...

    Text Solution

    |

  8. A compound of A, B and C has cubic close packed arrangement of A, B oc...

    Text Solution

    |

  9. The compound MO (molar mass = 100 g mol^(-1)) has zinc-blende structur...

    Text Solution

    |

  10. An ionic compound MX has rock-salt structure. If r(c)=120 pm and r(a)=...

    Text Solution

    |

  11. What is the density of Na(2)O having antifluorite-type crystal structu...

    Text Solution

    |

  12. In cubic ZnS if the radii of Zn^(2+) and S^(2-) atoms are 0.74 Å and 1...

    Text Solution

    |

  13. The gamma-form of iron has fcc structure (edge length 386 pm) and beta...

    Text Solution

    |

  14. An element forms crystals of density of 8570kgm^(-3). The packing effi...

    Text Solution

    |

  15. In bronze, copper forms fcc arrangement and tin occupies interstitial ...

    Text Solution

    |

  16. A metal of density 7.5xx10^(3) kg m^(-3) has an fcc crystal structure ...

    Text Solution

    |

  17. The ratio of the volume of a tetragonal lattice unit cell to that of a...

    Text Solution

    |

  18. The correct statement regarding defects in solids is

    Text Solution

    |

  19. A certain sample of cuprous sulphide is found to have composition Cu(1...

    Text Solution

    |

  20. Ammonium chloride crystallises in CsCl type (bcc) lattice with unit ce...

    Text Solution

    |