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According to freundlich adsorption isoth...

According to freundlich adsorption isotherm, which of the following is correct?

A

`(x // m) prop P^@`

B

`(x//m) prop P`

C

`(x//m) prop P`

D

All the above are correct for different ranges of Pressure

Text Solution

Verified by Experts

The correct Answer is:
D

Freundlich adsorption isotherm is generally represented as (x/m)= `kp^(1//n)` withn `gt` 1. However, this is valid for the limited range of pressure. At low pressure, x/m is generally vary linearly with pressure. Hence, (x/m) `prop` p. At high pressure, (w/m) attains a constant value. Hence, (x/m) `prop P^@` . In between these two ranges (x/m) does not increase as fast as pressure. Hence `(x//m) prop p^(1//a)` with `n gt 1`
Thus all the three choices are correct at different ranges of pressure.
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