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Which of the following are correct state...

Which of the following are correct statements

A

Spontaneous adsorption of gases on solid surface is an exotherinic process as entropy decreases during adsorption.

B

Fomation of micelles takes place when temperature is below Kraft Temperature (T) and concentration is above critical micelle concentration (CMC).

C

A colloid of `Fe(OH)_3` is prepared by adding a little excess (required to completely precipitate `Fe^(+3)` ion s as `Fe(OH)_3` of NaOH in `FeCl_3` solution, then particles of this sol will move towards cathode during electrophoresis.

D

According to Hardy-Schulze rule the coagulating (flocculating) value of `Fe^(3+)` ions will be more than `Ba^(2+)` or `Na^+`.

Text Solution

Verified by Experts

The correct Answer is:
A, C

A) `Delta G = Delta H - T Delta S lt 0`
As `Delta S lt 0 so Delta H` has to negative for spontaneous adsorptin.
(B) Micelles formtion will take place above `T_k` and above CMC.
(C) This solution will be negatively charged.
(D) `Fe^(3+)` ions will have greater coagulation power so smaller coagulation value.
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