Home
Class 12
CHEMISTRY
How tert-butyl bromide reacts with aqueo...

How tert-butyl bromide reacts with aqueous KOH ? Give the mechanism and kinetics of · reaction.

Text Solution

Verified by Experts

`underset("methy bromide (Aialky halide )")(CH_3 Br) + KOH (aq) overset(S_(N^2))to underset("Methyl alcohol")(CH_3 OH^(+) KBr)`
Mechanism of the reaction : The reaction follows `S_(N^2)` mechanism in case of `1^@` alkyl halides because of least steric hinderance.

Kinetics of the reaction : Rate of reaction `= k[CH_3Br[OH^(-)]` Order of reactivity of alkyl halides `S_(N^2)` mechanism : `3^@ lt 2^@ lt 1^@`
Promotional Banner

Topper's Solved these Questions

  • GENERAL PRINCIPLES AND PROCESS OF ISOLATION OF ELEMENTS

    BETTER CHOICE PUBLICATION|Exercise Question Bank (6.6 OXIDATION-REDUCTION)|15 Videos
  • ORGANIC COMPOUND WITH FUNCTIONAL GROUP CONTANING OXYGEN-II

    BETTER CHOICE PUBLICATION|Exercise Question Bank (12.9 Uses of Carboxylic Acids)|4 Videos

Similar Questions

Explore conceptually related problems

1,1-Dichloroethane reacts with aqueous KOH to give ethanol.

Give the mechanism of heterogeneous catalysed reaction.

tert-Butylbromide reacts with aq. NaOH by S_N1 mechanism while n-butylbromide reacts by S_N2 mechanism. Why ?

How do the products differ when ethyl bromide reacts separately with aqueous KOH and alcoholic KOH ? Name the products.

Calcium carbonate reacts with aqueous HCl to give CaCl_(2) and CO_(2) according to the reaction, CaCO_(3) (s) + 2HCl(aq)rarr CaCl_(2) (aq) + CO_(2)(g) + H_(2)O(l) What mass of CaCO_(3) is required to react completely wth 25mL of 0.75 M HCl?

An optically active compound having molecular formula C_7H_15Br reacts with KOH to give a racemic mixture of products. Write the mechanism involved for this reaction.

How does permanganate solution react with Fe(II) ions? Write balanced ionic equations for the reaction.

BETTER CHOICE PUBLICATION-HALOALKANES AND HALOARENES-QUESTIONS
  1. Give the reaction chloroform with alcoholic KOH.

    Text Solution

    |

  2. Explain with example S(N^1) mechanism.

    Text Solution

    |

  3. How tert-butyl bromide reacts with aqueous KOH ? Give the mechanism an...

    Text Solution

    |

  4. Explain SN^2 reactions. What is the preference order of different alky...

    Text Solution

    |

  5. How tert-butyl bromide reacts with aqueous KOH ? Give the mechanism an...

    Text Solution

    |

  6. Give the mechanism of substitution nucleophilic bimolecular, SN^2 reac...

    Text Solution

    |

  7. How tert-butyl bromide reacts with aqueous KOH ? Give the mechanism an...

    Text Solution

    |

  8. How does chlorobenzene reacts with the following: Sodium

    Text Solution

    |

  9. How does chlorobenzene reacts with the following: H2 SO4

    Text Solution

    |

  10. How does chlorobenzene react with : Mg.

    Text Solution

    |

  11. How does chlorobenzene reacts with the following: KCl2

    Text Solution

    |

  12. How does chlorobenzene react with: Lithium

    Text Solution

    |

  13. How does chlorobenzene react with: HNO3

    Text Solution

    |

  14. What happens when : Chlorobenzene is treated with CH3Cl in the prese...

    Text Solution

    |

  15. Explain the following reactions : Nitration of haloarenes.

    Text Solution

    |

  16. How does chlorobenzene react with sodium in the presence of ether ? Wh...

    Text Solution

    |

  17. How does chlorobenzene react with : Mg.

    Text Solution

    |

  18. How does chlorobenzene react with : Cl2.

    Text Solution

    |

  19. How does iodobenzene react with copper powder in a sealed tube ? What ...

    Text Solution

    |

  20. How does chlorobenzene react with methyl chloride iinn the presence of...

    Text Solution

    |