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Out of the following compounds , I)Pent-...

Out of the following compounds , I)Pent-1-ene , II)Pent-2-ene , III)2-Methyl but-1-ene , IV) 2-Methyl but-2-ene . Which pair has the lowest and the highest heats of combustion , respectively ?

A

(IV) and (I), respectively

B

(I) and (IV), respectively

C

(II) and (III), respectively

D

(III) and (II), respectively

Text Solution

Verified by Experts

The correct Answer is:
A

More-stable or more-substituted alkene has the lowest (more negative) `DeltaH_(c)^(@)`.
The order of stability of alkene : `IVgtIIIgtIIgtI`.
So the lowest `DeltaH_(c)^(@)` is of (IV) and the highest is of (I).
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