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3.7 g of a gas at 25^(@)C occupied the s...

`3.7 g` of a gas at `25^(@)C` occupied the same volume as `0.184 g` of hydrogen at `17^(@)C` and at the same pressure. The molecular mass of the gas is

A

0.024

B

39.14

C

41.33

D

59.14

Text Solution

Verified by Experts

The correct Answer is:
C

For hydrogen, w = 0.184 g , T = 17 + 273 = 290 K , M = 2
From pV = `(w)/(M) RT = (0.184)/(2) xx R xx 290 " "` … (i)
For unknown gas , w = 3.7 g T = 25 + 273 = 298 K , M = ?
`pV = (3.7)/(M) xx R xx 298`
From Eqs. (i) and (ii) `(3.7)/(M) xx R xx 298 = (0.184)/(2) xx R xx 290 or M = (3.7 xx 298 xx 2)/(0.184 xx 290) = 41.33`
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