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In which of the following arrangements, ...

In which of the following arrangements, the order is not correct according to the property indicated against it?

A

`CO_2 lt SiO_2 lt SnO_2 lt Pb O_2 ` : Increasing oxidizing power

B

`HF lt HCl lt HBr lt HI:` Increasing acidic strength

C

`NH_3 lt PH_3 lt AsH_3 lt SbH_3` Increasing basic strength

D

`B lt C lt O lt N` Increasing first ionization enthalpy

Text Solution

Verified by Experts

The correct Answer is:
C

Increasing order of basic strength: `SbH_3 lt ASH_3 lt PH_3 lt NH_3`, As the size of central atom increases, the electron density on the central metal atom decreases and consequently its tendency to donate a pair of electrons decreases. Hence, the basic strength decreases as we move from `NH_3` to `BiH_3`
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