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Which of the following statements are in...

Which of the following statements are incorrect?

A

Solid `PCl_5` exists as tetrahedral `[PCl_4]^(+)` and octahedral `[PCl_6]^(+)` ions.

B

Oxides of phosphorus, `P_2 O_3 and P_2 O_3` exist as monomers.

C

Solid `PCl_5` exists as `[PCI_4]^(+)CI^(-)`

D

Solid `N_2 O_5` exists as `NO_(2)^(+) NO_(3)^(-)`

Text Solution

Verified by Experts

The correct Answer is:
B, C

Oxides of phosphorus `P_2 O_3` and `P_2 O_5` exist as dimers, that is, `P_2 O_6 ` and `P_4 O_(10)` Solid `PCl_5`, exists as `[PCI_4]^(+) and [PCI_6]^(-)` .
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