The compound(s) that exhibit(s) geometri...

The compound(s) that exhibit(s) geometrical isomerism is (are)

`[Cr(NH_3)_5Cl]Cl_2 and [Cr(NH_3)_4Cl_2]Cl`

`[Co(NH_3)_4Cl_2]^(+) and [Pt(NH_3)_2(H_2O)Cl]^(+)`

`[CoBr_2Cl_2]^(2+) and [PtBr_2Cl_2]^(2-)`

`[Pt(NH_3)_3 (NO_3)] Cl and [Pt(NH_3)_3 Cl]Br`

Text Solution

Verified by Experts

The correct Answer is:

B, D

The complex `[Co(NH_3)_4 Cl_2]^(+) and [Pt(NH_3)_2 (H_2O)Cl]^(+)` both exhibit grometrical isomerism. The complex `[Pt(NH_3)_3(NO_3)]Cl and [Pt(NH_3)Cl]Br` both exhibit ionisation isomersm.

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Geometrical isomerism is shown by

` CH_2=C(Br) I`

`CH_3 CH=C (Br) I`

` (CH_3)_2 C=C(Cl) Br`

`CH_3 CH=C Cl_2`

Which of the following compounds will exhibit geometrical isomerism?

1-Phenyl-2-butene

3-Phenyl-1-butene

2-Phenyl-1-butene

1,1-Diphenyl-1-propene

Statement 1 , All compounds having C=C bond exhibit geometrical isomerism. Statement 2 : Rotation about C=C bond is restricted.

Statement 1 is True, statement 2 is True, Statement 2 is Correct explanation for Statement 5

Statement 1 is True, Statement 2 is True, Statement 2 is NOT a correct explanation for Statement 5

Statement 1 is True, Statement 2 is False.

Statement 1 is False, Statement 2 is True.