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Define activation energy of a reaction....

Define activation energy of a reaction.

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Arrhenius studies the effect of temperature on the rate of a reaction and postulted that rate constant varies with temperature exponentially as k=Ae^(E_(a)//RT) . Thuis method is generally used for finding the activation energy of a reaction. Keeping temperature constant, the effect of catalyst on the activation energy has also been studied. If the rate of reaction doubles for 10^(@)C rise of temperature form 290K to 300K, the activation energy of the reaction will be approximately: a) 40 Kcal mol^(-1) b) 12 Kcal mol^(-1) c) 60 Kcal mol^(-1) d) 70 Kcal mol^(-1)

True or False : Higher the activation energy of a reaction, faster is the reaction.

What is Arrhenius equation to describe the effect of temperature on rate of a reaction ? How can it be used to calculate the activation energy of a reaction ?

The activation energy of a reaction can be determined by

The rate of a particular reaction triples, when temperature changes from 50^(@)C to 100^(@). Calculate the activation energy of the reaction.

Enzymes are biocatalysts. They catalyse biochemical reactions. In general they reduce activation energy of reactions. Many physico-chemical processess are enzyme mediate. Some examples of enzyme mediated reactions are given below. Tick the wrong entry:

At 27^@C in the presence of a catalyst, the activation energy of a reaction is lowered by 10 kJ mol^-1 . The ratio of log k (catalyst)/k (uncatalysed) is

The activation energy of the reaction, A+BtoC+D+38 kcal is 20 kcal. What would be the activation energy of the following reaction. C+DtoA+B

MODERN PUBLICATION-CHEMICAL KINETICS-EXERCISE
  1. The reaction: A + 2B rarr C obeys rate equation. Rate = k [A]^(1//2) ...

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  2. Define order of a reaction.

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  3. Define activation energy of a reaction.

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  4. A first order reaction has a half life period of 34.65 seconds. Its ra...

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  5. If a graph is plotted between Iog k and 1/T the slope of the straight...

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  6. Reactions with very low activation energies are generally

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  7. Which of the following does not influence the reaction rate?

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  8. Unit of rate constant for zero order reaction is

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  9. A catalyst :

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  10. What is the unit of rate constant for second order reaction ?

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  11. The value of k for a reaction is 2.96xx10^(30)s^-1 , what is the order...

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  12. A reaction was found to be of second order with respect to concentrati...

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  13. What is the unit of rate of reaction ?

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  14. Half life period of a first order reaction is :

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  15. Calculate the half-life of a first order reaction from its rate consta...

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  16. The change in any one of the reactants or products per unit time is ca...

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  17. The rate of a reaction is 1.209 xx10^-4L^2 mol^-2 s^-1. The order of t...

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  18. A larger increase in reaction rate with small rise in temperature is d...

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  19. Discuss the various factors affecting the rates of chemical reactions.

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  20. What is meant by order of a chemical reaction ? The reaction : 2NO2 + ...

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