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Define activation energy of a reaction....

Define activation energy of a reaction.

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Arrhenius studies the effect of temperature on the rate of a reaction and postulted that rate constant varies with temperature exponentially as k=Ae^(E_(a)//RT) . Thuis method is generally used for finding the activation energy of a reaction. Keeping temperature constant, the effect of catalyst on the activation energy has also been studied. If the rate of reaction doubles for 10^(@)C rise of temperature form 290K to 300K, the activation energy of the reaction will be approximately: a) 40 Kcal mol^(-1) b) 12 Kcal mol^(-1) c) 60 Kcal mol^(-1) d) 70 Kcal mol^(-1)

True or False : Higher the activation energy of a reaction, faster is the reaction.

What is Arrhenius equation to describe the effect of temperature on rate of a reaction ? How can it be used to calculate the activation energy of a reaction ?

The activation energy of a reaction can be determined by

The rate of a particular reaction triples, when temperature changes from 50^(@)C to 100^(@). Calculate the activation energy of the reaction.

Enzymes are biocatalysts. They catalyse biochemical reactions. In general they reduce activation energy of reactions. Many physico-chemical processess are enzyme mediate. Some examples of enzyme mediated reactions are given below. Tick the wrong entry:

At 27^@C in the presence of a catalyst, the activation energy of a reaction is lowered by 10 kJ mol^-1 . The ratio of log k (catalyst)/k (uncatalysed) is

The activation energy of the reaction, A+BtoC+D+38 kcal is 20 kcal. What would be the activation energy of the following reaction. C+DtoA+B

MODERN PUBLICATION-CHEMICAL KINETICS-EXERCISE
  1. Deduce the rate equation for a zero order reaction.

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  2. The half life period for the decomposition of a compound is 20 min. If...

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  3. Define activation energy of a reaction.

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  4. Show that in case of a first order reaction, the time taken for comple...

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  5. Consider a general reaction aA+ bB rarr cC+ dD. The rate expression fo...

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  6. Consider a general reaction aA+ bB rarr cC+ dD. The rate expression fo...

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  7. “Reactions with zero order is possible, but zero molecularity is not”....

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  8. The term ‘order and molecularity ' are common in chemical kinetics. Wh...

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  9. The term ‘order and molecularity ' are common in chemical kinetics. Wr...

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  10. The term ‘order and molecularity ' are common in chemical kinetics. Wr...

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  11. Derive the integrated rate equation for the rate constant for a first ...

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  12. Differentiate between order and molecularity of a chemical reaction.

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  13. For the hydrolysis of methyl acetate in aqueous solution, the followin...

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  14. For the hydrolysis of methyl acetate in aqueous solution, the followin...

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  15. For a reaction: A+ B rarr P, the rate law is given as: Rate = k[A][B]^...

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  16. For a reaction: A+ B rarr P, the rate law is given as: Rate = k[A][B]^...

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  17. A first order reaction takes 30 minutes for 50 % completion. Calculate...

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  18. Explain the following terms : Rate of a reaction.

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  19. Define activation energy of a reaction.

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  20. The decomposition of phosphine, PH3, proceeds according to the followi...

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