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The integrated rate equations can be fit...

The integrated rate equations can be fitted with kinetic data to determine the order of a reaction. The integrated rate equations for zero, first and second order reactions are : Zero order : `[Al =-kt+ [A]_0` First order : `log [A] = -(kt)/2.303 + log [A]_0` Second order : `1/([A])=kt+1/[A]_0` These equations can also be used to calculate the halt life periods of different reactions, which give the time during which the concentration of a reactant is reduced to half of its initial concentration, i.e, at time `t_(1//2), [A] = [A]_0//2` Answer the following (1 to 5) question : The decomposition of nitrogen pentoxide : `2N_2O_5(g) rarr 4NO_2(g) + O_2(g)` is a first order reaction. The plot of log `[N_2O_5]` vs time (min) has slope = - 0.01389. The rate constant k is

A

`1.389xx10^-2 mi n^-1`

B

`3.2xx10^-2 mi n^-1`

C

`6.03xx10^-3 mi n^-1`

D

`71.99 mi n^-1`

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The integrated rate equations can be fitted with kinetic data to determine the order of a reaction. The integrated rate equations for zero, first and second order reactions are : Zero order : [Al =-kt+ [A]_0 First order : log [A] = -(kt)/2.303 + log [A]_0 Second order : 1/([A])=kt+1/[A]_0 These equations can also be used to calculate the halt life periods of different reactions, which give the time during which the concentration of a reactant is reduced to half of its initial concentration, i.e, at time t_(1//2), [A] = [A]_0//2 Answer the following (1 to 5) question : For a second order reaction, the correct plot of t_(1//2) vs. 1//[A]_0 is

The integrated rate equations can be fitted with kinetic data to determine the order of a reaction. The integrated rate equations for zero, first and second order reactions are : Zero order : [Al =-kt+ [A]_0 First order : log [A] = -(kt)/2.303 + log [A]_0 Second order : 1/([A])=kt+1/[A]_0 These equations can also be used to calculate the halt life periods of different reactions, which give the time during which the concentration of a reactant is reduced to half of its initial concentration, i.e, at time t_(1//2), [A] = [A]_0//2 Answer the following (1 to 5) question : For a second order reaction, rate at a particular time is x. if the initial concentration is tripled, the rate will become

The integrated rate equations can be fitted with kinetic data to determine the order of a reaction. The integrated rate equations for zero, first and second order reactions are : Zero order : [Al =-kt+ [A]_0 First order : log [A] = -(kt)/2.303 + log [A]_0 Second order : 1/([A])=kt+1/[A]_0 These equations can also be used to calculate the halt life periods of different reactions, which give the time during which the concentration of a reactant is reduced to half of its initial concentration, i.e, at time t_(1//2), [A] = [A]_0//2 Answer the following (1 to 5) question : The rate for the first order reaction is 0.0069 mol L^-1 mi n^-1 and the initial concentration is 0.2 mol L^-1 . The half life period is

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Calculate the half life period of first order reaction where the specific rate constant is 200 s^-1

MODERN PUBLICATION-CHEMICAL KINETICS-EXERCISE
  1. Consider the following reaction for 2NO2(g) + F2(g) rarr 2NO2F(g). The...

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  2. Arrhenius equation is

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  3. The integrated rate equations can be fitted with kinetic data to deter...

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  4. The integrated rate equations can be fitted with kinetic data to deter...

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  5. The integrated rate equations can be fitted with kinetic data to deter...

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  6. The integrated rate equations can be fitted with kinetic data to deter...

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  7. For a zero order reaction, linear plot was obtained for [A] vs t. The ...

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  8. According to collision theory of chemical reactions, rate of a reactio...

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  9. For a first order reaction, the plot of log K versus 1/T gives straigh...

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  10. The pre-expotential factor in Arrhenius equation of a second order rea...

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  11. At 27^@C in the presence of a catalyst, the activation energy of a rea...

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  12. The rate of a chemical reaction becomes double for every 10^@C rise in...

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  13. Fill in the blanks- is a mixture of and is used as an explosive.

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  14. What is the fraction of molecules having energy equal to or greater th...

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  15. The questions given below consist of an Assertion and a Reason. Use th...

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  16. Higher-order (n > 3) reactions are rare due to:

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  17. True or False : The half life Period for a first order reaction is ind...

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  18. Fill in the blanks- is an alloy which is used in the manufacture of l...

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  19. Assertion : For a second order reaction, graph of [A] vs. t is a strai...

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  20. Molecularity of a reaction cannot be zero.

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