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1.2 % NaCl solution is isotonic with 7.2...

1.2 % NaCl solution is isotonic with 7.2 % glucose solution. What will be the van't Hoff factor, i?

A

`0.5`

B

`1`

C

`2`

D

`6`

Text Solution

Verified by Experts

The correct Answer is:
C

For `NaCl pV = nST xx i`
`p_i xx 100/1000 = 1.2/58.5 xx 0.821 xx T xx i " " ...(i)`
For glucose, `pV = nST`
`p_2 xx 100/100 = 7.2/180 xx 0.0821 xx T " "…(ii) `
`because NaCl` and glucose solutions are isotonic
`therefore p_1 = p_2`
On dividing Eq. (i) by (ii), we have
`i = 7.2/180 xx 58.5/1.2 = 1.95= 2`
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