Home
Class 12
CHEMISTRY
Both [Ni(CO)4] and [Ni(CN)4]^(2-) are di...

Both `[Ni(CO)_4]` and `[Ni(CN)_4]^(2-)` are diamagnetic. The hybridisations of nickel in these complexes respectively are

A

`dsp^2` in both

B

`sp^3` in both

C

`dsp^3` in cyano and `sp^3` in chloro complex

D

`sp^3` in cyano complex and `dsp^3` in chloro complex.

Text Solution

Verified by Experts

Promotional Banner

Topper's Solved these Questions

  • COORDINATION COMPOUNDS

    MODERN PUBLICATION|Exercise EXERCISE|971 Videos
  • CHEMISTRY IN EVERYDAY LIFE

    MODERN PUBLICATION|Exercise EXERCISE|352 Videos
  • d-AND f- BLOCK ELEMENTS

    MODERN PUBLICATION|Exercise EXERCISE|1089 Videos

Similar Questions

Explore conceptually related problems

Name the hybridisation of Ni in [Ni(CO)_4]

[Ni(CN)_4]^(2-) is diamagnetic and has ............. shape.

Explain: [Ni (CN)_4]^(2-) is diamagnetic while [Ni(Cl)_4]^(2-) is paramagnetic.

Explain, Why [Ni(CO)_4] is diamagnetic whereas [NiCl_4]^(2-) is paramagnetic ?

Nickel (Z = 28) combines with a uninegative monodentate ligand X to form a paramagnetic complex [NiX_4]^(2-) . The number of unpaired electron(s) in the nickel and geometry of this complex ion are, respectively

For the complex [NiCl_4]^(2-) , write the hybridisation type. (Atomic no. of Ni = 28)

Explain as to how the two complexes of nickel, [Ni(CN)_4]^(2-) and [Ni(CO)_4] have different structure but they donot differ in their magnetic behaviour.

[Cr(NH_3)_6]^(3+) is paramagnetic while [Ni(CN)_4]^(2-) is diamagnetic. Explain why?

NiCl_2[P(C_2H_5)_2 (C_6H_5)]_2 exhibits temperature dependent magnetic behaviour (paramagnetic/diamagnetic). The coordination geometries of Ni^(2+) in the paramagnetic and diamagnetic states are respectively

The hybridization of central metal ion in K_2[Ni(CN)_4] and K_2[NiCl_4] are respectively

MODERN PUBLICATION-COORDINATION COMPOUNDS-EXERCISE
  1. Ni^(2+) overset (KCN) rarr Complex 1 Ni^(2+) overset (excess) underse...

    Text Solution

    |

  2. What is correct regarding leucocytes?

    Text Solution

    |

  3. Both [Ni(CO)4] and [Ni(CN)4]^(2-) are diamagnetic. The hybridisations ...

    Text Solution

    |

  4. A metal complex having the molecular formula Cr(NH3)4Cl2,Br have been ...

    Text Solution

    |

  5. Both [Ni(CO)4] and [Ni(CN)4]^(2-) are diamagnetic. The hybridisations ...

    Text Solution

    |

  6. Choose the correct option- Artificial gold has the following compositi...

    Text Solution

    |

  7. Choose the correct option- Coin metal has the following composition-

    Text Solution

    |

  8. Choose the correct option- Gun metal has the following composition-

    Text Solution

    |

  9. The magnetic moment is a

    Text Solution

    |

  10. Which of the following does not exist? XeOF4, NeF2, XeF2, XeF6.

    Text Solution

    |

  11. The magnetic moment is a

    Text Solution

    |

  12. Find a relation between x and y if the points ( x,y), (1,2) and (7, 0)...

    Text Solution

    |

  13. Number of possible isomers for the complex [Co(en)2Cl2]Cl will be : (e...

    Text Solution

    |

  14. Number of possible isomers for the complex [Co(en)2Cl2]Cl will be : (e...

    Text Solution

    |

  15. Constantin has the following composition-

    Text Solution

    |

  16. Grignard's Reagent is

    Text Solution

    |

  17. The questions given below consist of an Assertion and Reason. Assert...

    Text Solution

    |

  18. Assertion : The complex ion trans-[Co(en)2Cl2]^+ is optically active. ...

    Text Solution

    |

  19. Assertion : NF3 is weaker ligand than N(CH3)3). Reason : NF3 ionises t...

    Text Solution

    |

  20. Assertion : The [Ni(en)3]Cl2 (en = ethylenediamine) has lower stabilit...

    Text Solution

    |