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Chlorobenzene and benzyl chloride can be...

Chlorobenzene and benzyl chloride can be distingulshed by boiling with aqueous KOH follwed by acidification with dil `HNO_3` and subsequent treatment with `AgNO_3` solution.

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In qualitative analysis when H_2S is passed through an aqueous solution of salt acidified with dil. HCl, a black precipitate is obtained. On boiling the precipitate with dil. HNO_3 , it forms a solution of blue colour. Addition of excess of aqueous solution of ammonia to this solution gives _______ .

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An aqueous solution of [Pt(NH_3)_2Cl_2] gives white precipitate of AgCl with AgNO_3(aq) .

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Acid-base indicators are either weak organic acids or weak organic bases. Indicator change colour in dilute solution when the hydonium ion concentration reaches a particular calur For example. Phenolphthalein is a coloureless stbstance in any aqueous solution with a pH less than 8.3 In between the pH range 8.3 to 10, transition of colour (colourless to pink ) takes place and if pH of solution is greater than 10 solution is dark pink. Considering an acid indicator Hln, the equilibrium involving it and its conjgate base In^(-) can be represented as : " " underset("acidic from")(HIn)hArrH^(+)underset("basic from")(In^(-)) pH of solution can be computed as : " " pH=pK_(In)+log.([IN^(-)])/([HIn]) In general, transition of colour takes place in between the pH range pK_(In+-1. Select the correct statement (s) :

Enthalpy of neutralzation is defined as the enthalpy change when 1 mole of acid /base is completely neutralized by base // acid in dilute solution . For Strong acid and strong base neutralization net chemical change is H^(+) (aq)+OH^(-)(aq)to H_(2)O(l) Delta_(r)H^(@)=-55.84KJ//mol DeltaH_("ionization")^(@) of aqueous solution of strong acid and strong base is zero . when a dilute solution of weak acid or base is neutralized, the enthalpy of neutralization is somewhat less because of the absorption of heat in the ionzation of the because of the absorotion of heat in the ionization of the weak acid or base ,for weak acid /base DeltaH_("neutrlzation")^(@)=DeltaH_("ionization")^(@)+ Delta _(r)H^(@)(H^(+)+OH^(-)to H_(2)O) What is DeltaH^(@) for complate neutralization of strong diacidic base A(OH)_(2)by HNO_(3) ?

MODERN PUBLICATION-HALOALKANES AND HALOARENES-EXERCISE
  1. True of False : CH3CH=CHCl is more reactive than ClCH2CH=CH2.

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  2. 2,3,4-trichloropentane has three asymmetric carbon atoms.

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  3. Chlorobenzene and benzyl chloride can be distingulshed by boiling with...

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  4. True of False : Addition of BrCCl3 to propene in the presence of perox...

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  5. True of False : lodide ion is a better nucleophile than bromide ion.

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  6. Chlorobenzene gives a white precipitate with alcoholic silver nitrate ...

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  7. True of False : 3, 3-Dimethylbut-1-ene reacts with HI to form 2-iodo-3...

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  8. True of False : Bromoethane reacts with silver nitrite to form ethyl n...

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  9. 1,1-Dichloroethane reacts with aqueous KOH to give ethanol.

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  10. True of False : Thioethers are obtained by reacting alkyl halides with...

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  11. Boiling point of iodobenzene is more than that of bromobenzene.

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  12. Complete the missing blanks : Isobutyl bromide is an example of.........

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  13. When alkyl halides are treated with Ag2O they give

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  14. Hydrolysis of 2-bromo-3-methylbutane gives ............. the major pro...

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  15. Write the oxidation number of central atom in the following compound :...

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  16. Express 1658 in roman numbers.

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  17. Chlorobenzene on reduction with Ni/Al alloy and alcohol gives ...........

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  18. Write the oxidation number of central atom in the following compound :...

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  19. Write the oxidation number of central atom in the following compound :...

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  20. Write the oxidation number of central atom in the following compound :...

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