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Assertion : Complexes of MX6 and MX5L ty...

Assertion : Complexes of `MX_6` and `MX_5L` type (X and L are unidentate) do not show geometrical isomerism. Reason : Geometrical isomerism is not shown be complexes of coordin-ation number 6.

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Which type of complexes do not show geometrical isomerism ?

True of False : All tetrahedral complexes show geometrical isomerism.

What type of isomerism is shown by the following complex , [Co(NH_3)_6][Cr(CN)_6] ?

The complexes [Co(NH_3)_6] [Cr(CN)_6] and [Cr(NH_3)_6] [Co(CN)_6] are examples of coordination isomerism/ coordination position isamerism.

Assertion : Lanthanoids show a limited number of oxidation states whereas actinoids show a large number of oxidation states. Reason : Energy gap between 4f, 5d and 6s subshells is small whereas that between 5f. 6d and 7s subshells is large.

The complexes [Co(NH_3)_6][Cr(CN)_6] and [Cr(NH_3)_6] [Co(CN)_6] are the examples of which type of isomerism ?

Assertion : Actinoids form relatively less stable complexes as compared to lanthanoids. Reason : Actinoids can utilise their 5f orbitals along with 6d orbitals in bonding but lanthanoids do not use their 4f orbital for bonding.

If l and m are variable real numbers such that 5l^2-4lm+6m^2+3l=0 , then the variable line lx+my=1 always touches a fixed parabola, whose axis is parallel to the X-axis. If (c,d) is the focus of the parabola , then the value of 2^|d-c| is

A ray of light comes light comes along the line L = 0 and strikes the plane mirror kept along the plane P = 0 at B. A(2, 1, 6) is a point on the line L = 0 whose image about P = 0 is A' . It is given that L = 0 is (x-2)/(3)= (y-1)/(4)= (z-6)/(5) and P =0 is x+y-2z=3 . The coordinates of B are

MODERN PUBLICATION-COORDINATION COMPOUNDS-EXERCISE
  1. Write the number of unpaired electron in given compound : [Cr(H2O)6]Cl...

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  2. Assertion : Linkage isomerism arises in coordination compounds contain...

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  3. Assertion : Complexes of MX6 and MX5L type (X and L are unidentate) do...

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  4. Assertion : ([Fe(CN)6]^(3-) ion shows magnetic moment corresponding to...

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  5. Give one example of linkage isomer.

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  6. Why does NH3 readily form complexes but NH4^(+) does not ?

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  7. Give evidence that [CO(NH3)5Cl]S04 and [CO(NH3)5(S04)]Cl are ionisati...

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  8. Name central metal atom present in haemoglobin and Vitamin B12.

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  9. Name one example of a hexadentate ligand.

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  10. Write the IUPAC name of the following : K3[Fe (CN)5 NO]

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  11. Write the IUPAC name of the compound [Cr(NCS)(NH3)5] [ZnCl4].

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  12. Draw the structures of optical isomers of: [Cr(C2O4)3]^3-

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  13. Draw the structures of optical isomers of : Cr(NH3)2Cl2 (en)]^+

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  14. The hexaquo manganese(II) ion contains five unpaired electrons, while ...

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  15. What is meant by stability of a coordination compound in solution? Sta...

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  16. Explain non-ionic nature of CoCl3 .3NH3 on the basis of Werner’s coord...

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  17. Write the shape and magnetic behaviour of the following complex : [Ni(...

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  18. On the basis of valence bond theory, explain the shape and magnetic be...

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  19. Write the shape and magnetic behaviour of the following complex : [Co(...

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  20. One mole of complex compound Co(NH3)5Cl3 give 3 moles of a ions on di...

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