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Convert phenol into: Benzene....

Convert phenol into: Benzene.

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Phenol associates in benzene to form a dimer (C_6H_5OH)_2 . The freezing point of a soluton contianing 5 g of phenol in 250 g of benzene is lowerd by 0.70^@C . Calculate the degree of association of phenol in benzene. (K_f for benzene=5.12 Km^-1)

MODERN PUBLICATION-ALCOHOLS, PHENOLS AND ETHERS-EXERCISE
  1. Why primary alcohols are more acidic than secondary alcohols?

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  2. How is phenol converted into salicylaldehyde ?

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  3. Convert phenol into: Benzene.

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  4. How is phenol converted into picric acid ?

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  5. Out of phenol and benzene which is more easily nitrated and why ?

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  6. Account for the following : How will you convert benzene diazonium chl...

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  7. Write short notes on the following : Friedel-Craft’s alkylation.

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  8. Complete the following reaction : CH3 CH2OH +[O] overset (K2Cr2O7) und...

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  9. Write short notes on : Wurtz reaction

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  10. Write short notes on the Finkelstein reaction

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  11. Write short notes on: Saytzeff’s rule.

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  12. Complete the following reaction : CH2= CH2+O3 rarr ? overset (H2O, Zn)...

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  13. Give the structural formulae and IUPAC names of the isomers with the m...

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  14. Phenol is usually manufactured from cumene. Write the structure of cum...

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  15. Primary, secondary and tertiary alcohols can be distinguished by Lucas...

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  16. Primary, secondary and tertiary alcohols can be distinguished by Lucas...

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  17. What happens when phenol is treated with CO2 at 4-7 atm pressure. Give...

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  18. What happens when phenol is treated with Br2//CS2. Give reaction also.

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  19. What happens when phenol is treated with CHCl3, NaOH at 340 K . Give r...

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  20. How will you distinguish between isopropyl alcohol and ethyl alcohol.

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