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For a reaction, A + B^(2+) rarr B + A^(2...

For a reaction, `A + B^(2+) rarr B + A^(2+)`, at `25^(@)C`
`E^(@)= 0.2955V`. The value of `K_(eq)` is

A

10

B

`10^(10)`

C

`-10`

D

`10^(-10)`

Text Solution

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The correct Answer is:
To find the equilibrium constant \( K_{eq} \) for the reaction \( A + B^{2+} \rightleftharpoons B + A^{2+} \) at \( 25^\circ C \) with a standard cell potential \( E^\circ = 0.2955 \, V \), we can use the Nernst equation and the relationship between the standard cell potential and the equilibrium constant. ### Step-by-Step Solution: 1. **Identify the Reaction and Standard Cell Potential:** The reaction is given as: \[ A + B^{2+} \rightleftharpoons B + A^{2+} \] The standard cell potential \( E^\circ \) is provided as \( 0.2955 \, V \). 2. **Use the Nernst Equation:** The Nernst equation relates the standard cell potential to the equilibrium constant: \[ E^\circ = \frac{0.0591}{n} \log K_{eq} \] where \( n \) is the number of moles of electrons transferred in the reaction. 3. **Determine \( n \):** In the given reaction, \( A \) is oxidized to \( A^{2+} \) and \( B^{2+} \) is reduced to \( B \). Since \( A \) loses 2 electrons to become \( A^{2+} \), we have: \[ n = 2 \] 4. **Substitute Values into the Nernst Equation:** Rearranging the Nernst equation to solve for \( K_{eq} \): \[ K_{eq} = 10^{\frac{n \cdot E^\circ}{0.0591}} \] Substituting \( n = 2 \) and \( E^\circ = 0.2955 \, V \): \[ K_{eq} = 10^{\frac{2 \cdot 0.2955}{0.0591}} \] 5. **Calculate \( K_{eq} \):** First, calculate the exponent: \[ \frac{2 \cdot 0.2955}{0.0591} \approx \frac{0.591}{0.0591} \approx 10.01 \] Therefore, \[ K_{eq} \approx 10^{10.01} \approx 10^{10} \] 6. **Final Result:** Thus, the value of \( K_{eq} \) is approximately: \[ K_{eq} \approx 10^{10} \]

To find the equilibrium constant \( K_{eq} \) for the reaction \( A + B^{2+} \rightleftharpoons B + A^{2+} \) at \( 25^\circ C \) with a standard cell potential \( E^\circ = 0.2955 \, V \), we can use the Nernst equation and the relationship between the standard cell potential and the equilibrium constant. ### Step-by-Step Solution: 1. **Identify the Reaction and Standard Cell Potential:** The reaction is given as: \[ A + B^{2+} \rightleftharpoons B + A^{2+} ...
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