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Which of the following is the correct or...

Which of the following is the correct order of stability of conformations for `NH_(2)-CH_(2)-CH_(2)-OH`

A

gauche `gt` eclipsed `gt` anti

B

gauche `gt` anti `gt` eclipsed

C

eclipsed `gt` gauche `gt` anti

D

anti `gt` eclipsed `gt` gauche

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The correct Answer is:
To determine the correct order of stability of conformations for the molecule NH₂-CH₂-CH₂-OH, we need to analyze the different conformations: anti, gauche, and eclipsed. ### Step-by-Step Solution: 1. **Identify the Conformations**: - The three main types of conformations are: - **Anti**: The substituents are positioned opposite to each other, minimizing steric hindrance. - **Gauche**: The substituents are positioned next to each other, leading to some steric strain but allowing for potential hydrogen bonding. - **Eclipsed**: The substituents are aligned with each other, leading to maximum steric hindrance and torsional strain. 2. **Draw the Conformations**: - **Anti Conformation**: In this conformation, the NH₂ and OH groups are positioned 180 degrees apart, which minimizes steric interactions. - **Gauche Conformation**: In this conformation, the NH₂ and OH groups are positioned 60 degrees apart. This allows for some interaction between the groups, such as hydrogen bonding, but also introduces some steric strain. - **Eclipsed Conformation**: In this conformation, the NH₂ and OH groups are aligned with each other (0 degrees apart), leading to maximum steric hindrance and torsional strain. 3. **Evaluate Stability**: - The **Eclipsed** conformation is the least stable due to high steric hindrance and torsional strain. - The **Gauche** conformation is more stable than eclipsed because of the possibility of hydrogen bonding, but less stable than anti due to some steric strain. - The **Anti** conformation is the most stable as it minimizes steric hindrance and allows for optimal spatial arrangement of the groups. 4. **Order of Stability**: - Based on the analysis, the correct order of stability for the conformations of NH₂-CH₂-CH₂-OH is: - Anti > Gauche > Eclipsed ### Final Answer: The correct order of stability of conformations for NH₂-CH₂-CH₂-OH is: **Anti > Gauche > Eclipsed**

To determine the correct order of stability of conformations for the molecule NH₂-CH₂-CH₂-OH, we need to analyze the different conformations: anti, gauche, and eclipsed. ### Step-by-Step Solution: 1. **Identify the Conformations**: - The three main types of conformations are: - **Anti**: The substituents are positioned opposite to each other, minimizing steric hindrance. - **Gauche**: The substituents are positioned next to each other, leading to some steric strain but allowing for potential hydrogen bonding. ...
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