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The heat of reaction for, C(10)H(8)+12O(...

The heat of reaction for, `C_(10)H_(8)+12O_(2(g)) rarr 10CO_(2(g))+4H_(2)O_((l))` at constant volume is `-1228.2 kcal` at `25^(@)C`. Calculate the heat of reaction at constant pressure at `25^(@)C`.

A

`-1228.2` kcal

B

`-1229.3 ` kcal

C

`-1232.9` kcal

D

`-1242.6` kcal

Text Solution

Verified by Experts

The correct Answer is:
A

`C_(18) H_(18) (s) +12O_(2) (g) rarr 10CO_(2) (g) + 4 H_(2) O(l)`
We known that `Delta H= Delta E + Delta ng RT`
`Delta ng=10-12 =-2`
`Delta H = -1228.2xx 10^(3) + (-2) xx 2xx298`
= - 1229393 Ca
= - 1229.39 kcal
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