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When 20 g of naphthoic acid (C2H8O2) is ...

When 20 g of naphthoic acid `(C_2H_8O_2)` is dissolved in 50 gofbenzene `(K_f "=1.72 K kg mol"^(-1)),` a freezing point depression of 2 K is observed. The van't Hoff factor (i) is

A

`0.5`

B

1

C

2

D

3

Text Solution

Verified by Experts

The correct Answer is:
A

Molality can be calculated using gien values as `m=(w_(A))/(M_(A) xx w_(B))xx 1000= (20)/(172 xx 50)xx 1000`
Therefore, `Delta T_(f)= ixx K_(f) xx m rArr 2 =I xx 1.72 xx (20)/(172 xx 50)xx 1000 rArr i=0.5`
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