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Explain Schottky defect....

Explain Schottky defect.

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Statement : Schottky defect is generally shown by the compounds with high co - ordination no. Explanation : Equal no. of cations and anions are missing from the lattice sites in Schottky defect.

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(a) Calculate the number of unit cell in 8.1g of aluminium if it crystallises in a fcc structure. (Atomic mass of Al = 27 g*mol^(-1) ) (b) Give reasons: (i) In stoichiometric defects, NaCl exhibits Schottky defect and not Frenkel defect. (ii) Silicon on doping with Phosphorous forms n-type semiconductor. (iii) Ferrimagnetic substances show better magnetism than anti-ferromagnetic substances.

Silver crystallises in face-centred cubic lattice. If edge length of the unit cell is 4.07xx10^(-8)cm and density of silver is 10.48g*cm^(-3) , determine the relative atomic mass of silver. or, (i) What is Schottky defect? (ii) Find out packing efficiency in a simple cubic lattice.