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Rate constant for a chemical reaction ta...

Rate constant for a chemical reaction taking place at 500 K is expressed as `k=A*e^(-1000)`. The activation energy of the reaction is `yxx 10^(6)"cal mol"^(-1)`. y is ______. `[R=2"cal mol"^(-1)K^(-1)]`

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To solve the problem, we need to find the value of \( y \) in the expression for activation energy given as \( y \times 10^6 \) cal/mol. We will use the Arrhenius equation to relate the rate constant \( k \) to the activation energy \( E_a \). ### Step-by-Step Solution: 1. **Understand the Given Information:** - The rate constant \( k \) is expressed as: \[ k = A e^{-1000} \] - The activation energy \( E_a \) is given as: \[ E_a = y \times 10^6 \text{ cal/mol} \] - The gas constant \( R \) is: \[ R = 2 \text{ cal mol}^{-1} \text{ K}^{-1} \] - The temperature \( T \) is: \[ T = 500 \text{ K} \] 2. **Use the Arrhenius Equation:** The Arrhenius equation relates the rate constant \( k \) to the activation energy \( E_a \): \[ k = A e^{-\frac{E_a}{RT}} \] By comparing the two expressions for \( k \), we have: \[ e^{-1000} = e^{-\frac{E_a}{RT}} \] 3. **Equate the Exponents:** Since the bases are the same, we can equate the exponents: \[ -1000 = -\frac{E_a}{RT} \] This simplifies to: \[ 1000 = \frac{E_a}{RT} \] 4. **Solve for Activation Energy \( E_a \):** Rearranging gives: \[ E_a = 1000 \times RT \] Now substitute the values of \( R \) and \( T \): \[ E_a = 1000 \times (2 \text{ cal mol}^{-1} \text{ K}^{-1}) \times (500 \text{ K}) \] 5. **Calculate \( E_a \):** \[ E_a = 1000 \times 2 \times 500 = 1000 \times 1000 = 10^6 \text{ cal/mol} \] 6. **Compare with Given Expression:** We have found that: \[ E_a = 10^6 \text{ cal/mol} \] This can be expressed as: \[ E_a = 1 \times 10^6 \text{ cal/mol} \] Therefore, comparing with \( E_a = y \times 10^6 \text{ cal/mol} \), we find: \[ y = 1 \] ### Final Answer: The value of \( y \) is \( 1 \).

To solve the problem, we need to find the value of \( y \) in the expression for activation energy given as \( y \times 10^6 \) cal/mol. We will use the Arrhenius equation to relate the rate constant \( k \) to the activation energy \( E_a \). ### Step-by-Step Solution: 1. **Understand the Given Information:** - The rate constant \( k \) is expressed as: \[ k = A e^{-1000} ...
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