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Which one of the following is the interm...

Which one of the following is the intermediate in the preparation of a ketone by hydration of an alkyne in the presence of sulfuric acid and mercury (II) sulphate ?

A

B

C

D

Text Solution

Verified by Experts

The correct Answer is:
D

Reaction proceed throgh enol format on and `H_(2)O` attack on stable carbocation in this reaction.
`therefore` (d) is most favourable. (Kucherov reaction)
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MS CHOUHAN-HYDROCARBONS (ALKYNES)-Level -1
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  2. Which combination is best for preparation of the compound (A) shown be...

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  3. Which one of the following is the intermediate in the preparation of a...

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  4. To carry out above conversion , (A) and (B) respectively, are :

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  5. H-C-=C-Ph , Product obtained in this reaction is :

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  6. CH underset((ii) CH(3)Br)overset((i) NaNH(2), NH(3))rarr (A) underset(...

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  7. Which of the following alkyne on treatment with H(2) (2 mole)/Pt gives...

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  8. underset("(Calcium carbide)")(CaC(2)) overset(H(2)O)rarr (A) overset("...

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  9. What is the final product, C, of the following reaction sequence ?

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  10. Compound (X) will be :

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  11. Choose the sequence of steps that describes the best synthesis of 1-bu...

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  12. Which alkyne yields butanoic acid (CH(3)CH(2)CH(2)CO(2)H) as the only ...

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  13. (A) Unit of unsaturation in compound (A) ?

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  14. product (C) of above reaction is :

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  15. To convert 1-butyne to 1-D-butanal, one would carry out the following ...

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  16. An unknown compound (A) has a molecular formula C(4)H(6). When (A) is ...

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  17. 1, 2-Dibromo propane on treatment with X moles of NaNH(2) followed by ...

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  18. CH(3)-overset(CH(3))overset(|)(CH)-C-=CH overset("excess HBr")rarr T...

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  19. CH(3)-C-=C-CH(3) overset("Cold " KMnO(4))rarr (A) product (A) is :

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  20. In which reaction last product is Ph-C-=CH ?

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