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Ethanol when reacts with PCl5 gives A, P...

Ethanol when reacts with `PCl_5` gives A, `POCl_3` and HCl. A reacts with dry `AgO_2` to form B (major product) and AgCl. A andB respectively are:

A

`C_2H_2Cl and C_2H_5OC_2 H_5`

B

`C_2H_4 and C_2H_4OC_2H_5`

C

`C_2H_6 and C_2H_5OC_2H_5`

D

`C_2H_6 and C_2H_5NO_2`

Text Solution

Verified by Experts

`CH_3-CH_(2)-OH overset(PCl_5) rarr underset(CH_3CH_2-NO_2)underset(darrAgNO_2)(CH_3-CH_2 Cl + POCl_3 )+ HCl`
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Knowledge Check

  • Ethanol when reacted with Pcl_5 gives A, POCl_3 and Hcl. A reacts with silver nitrite to from B (major produced) and AgCl. A and B respectively are

    A
    `C_2H_5Cl` and `C_2H_5OH`
    B
    `C_2H_6` and `C_2H_5OC_2H_5`
    C
    `C_2H_6Cl` and `C_2H_5NO_2`
    D
    `C_2H_6` and `C_2H_5ONO`.

  • Phenol reacts with methyl chloroformate in the presence of NaOH to form product A. A reacts with Br_2 to form product B. A and B are respectively

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  • Thermal decomposition of a Mn compounds (X) at 513 K result in compounds Y, MnO_2 and a gaseous product MNO_2 reacts with NaCl and concentrated H_2SO_4 to give a pungent gas Z. X,Y and Z respectively are:

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    B
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    D
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