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Above reaction is a Baeyer Villiger rear...


Above reaction is a Baeyer Villiger rearrangement of an asymmetric ketone with magnesium mono peroxo pthalate hexahydrate (in the drawing, `Mg^(+2)` is omitted for clearity) Identify major product.

A

B

C

D

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The correct Answer is:
B
Oxidation of ketone will take place. (Insertion of oxyegn take place in between)
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Di-tert-glycols rearrange in the presence of acid to give alpa -tertiary ketones. The trivial name of the simplest glycol of this type is pinacol, and this type of reaction therefore is named pinacol rearrangement (in this specific case, the reaction is called a pinacol-pinacolone rearrangement). The rearrangement involves 4 steps. one of the hydroxyl groups is protonated in the first step. A molecule of water is eliminated in the second step and a tertiary carbocation is formed. The carbocation rearranges in the third step into a more stable carboxonium ion via a [1,2] rearrangement. In the last step, the carboxonium ion is deprotonated and the product ketone is obtained. How many products obtained in above reaction?

CH_(3)-CH=CH_(2) underset("h v (low conc.)")overset(Br_(2))rarr underset("Dry ether")overset(Mg)rarr underset(NH_(4)Cl)overset(CH_(3)-overset(O)overset(||)(C)-CH_(3))rarr underset(Delta)overset(H^(+))rarr underset("(major)")((X)) End product (X) of the above reaction is :

MS CHOUHAN-ALDEHYDES AND KETONES-LEVEL-2
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  2. Select the best choice for example (A to L) from the examples (a to n)...

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  3. The following questions refer to the compounds (A to G) shown below :

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  4. Match of the column :

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  5. Complete the following table.

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  6. Consider the following reactions and answer A and B. Suggest a re...

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  7. Consider the following reactions and answer A and B. Yield of eac...

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  8. Degree of unsaturation present in compound (A + B + C) is ?

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  9. Within each set, which compound should be more reactive toward carbony...

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  10. Match the Column (I) and Column (II). (Matrix)

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  11. Consider reactions A through F. Those carbon atoms undergoing change, ...

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  12. Consider the possible formation of an aldehyde or ketone product when ...

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  13. Wittig reaction : The reaction of a phosphorus ylide with an aldehyd...

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  14. Wittig reaction : The reaction of a phosphorus ylide with an aldehyd...

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  15. Wittig reaction : The reaction of a phosphorus ylide with an aldehyd...

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  16. Wittig reaction : The reaction of a phosphorus ylide with an aldehyd...

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  17. Wittig reaction : The reaction of a phosphorus ylide with an aldehyd...

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  18. Wittig reaction : The reaction of a phosphorus ylide with an aldehyd...

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  19. Match the column :

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  20. Reactant (A) is :

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  21. Product (B) is :

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