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CH(3)-overset(O)overset(||)(C)-OHunderse...

`CH_(3)-overset(O)overset(||)(C)-OHunderset(Delta)overset(Ca(OH)_(2))to(A)`
Product (A) is :

A

B

C

D

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The correct Answer is:
B
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CH_(3)CH_(2)-overset(O)overset(||)(C)-CH_(3)underset(HCl)overset(NaNO_(2))to , Major product of this reaction is :

Wittig reaction : The reaction of a phosphorus ylide with an aldehyde (or) ketone introduces a carbon-carbon double bond is place of the carbonyl bond. Driving froce of the reaction is high bond energy of (P = O). (DeltaH=-ve) . CH_(3)-overset(O)overset(||)(C)-CH_(2)-CH_(2)-CH_(2)-CH_(2)-overset(o+)(P)Ph_(3)underset(Delta)overset(Ph-Li)to(A) , Major product (A) is :

underset("(excess)")(CH_(3)MgBr) + Et - O-overset(O)overset(||)(C)-O -Et underset((2) H^(o+))rarr (A) , Product A is :

CH_(3)-CH=CH_(2) underset("h v (low conc.)")overset(Br_(2))rarr underset("Dry ether")overset(Mg)rarr underset(NH_(4)Cl)overset(CH_(3)-overset(O)overset(||)(C)-CH_(3))rarr underset(Delta)overset(H^(+))rarr underset("(major)")((X)) End product (X) of the above reaction is :

CH_3 - CH_2 - CH_2 - CH_2 - underset(CH_3) underset(|)overset(CH_3)overset(|)C-CH_2 -OH underset(Delta) overset(H^(+))to underset(("major"))(A) product (A) is :

Ph - CH_(2) - overset(O)overset(||)(C) - OH underset((2)H^(oplus))overset((1)NaOH,CaO,Delta)(rarr)(A) Product (A) is :

CH_(3)-overset(O)overset(||)(C)-O-H overset(NaH overset(14)(CO_(3)))rarr underset("(gas)")((A)) underset((ii) H_(3)O^(o+))overset((i) PhMgBr)rarr (B) CH_(3)-underset(O)underset(||)overset(O)overset(||)(S)-O-H overset(NaHoverset(14)(CO_(3)))rarr underset("gas")((C )) underset((ii) H_(3)O^(o+))overset((i) PhMgBr)rarr (D) Product (B) and (D) in the above reaction are :

overset(Ac_(2)O)(to)Poverset(Ac_(2)O)(to)Q Ac_(2)O=CH_(3)-overset(O)overset(||)(C )-O-overset(O)overset(||)(C )-CH_(3) P and Q respectively are :

Write the IUPAC name of compound: CH_(3)-overset(O)overset(||)(C)-CH=overset(CH_(3))overset(|)(C)-CH_(3)

Ph - CH_2 underset(OH)underset(|)CH-CH_3 overset(K) rarr overset(C_2H_2Br)rarr (A) Product (A) in above reaction is :

MS CHOUHAN-ALDEHYDES AND KETONES-LEVEL-2
  1. CH(3)-overset(O)overset(||)(C)-OHunderset(Delta)overset(Ca(OH)(2))to(A...

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  2. Select the best choice for example (A to L) from the examples (a to n)...

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  3. The following questions refer to the compounds (A to G) shown below :

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  4. Match of the column :

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  5. Complete the following table.

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  6. Consider the following reactions and answer A and B. Suggest a re...

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  7. Consider the following reactions and answer A and B. Yield of eac...

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  8. Degree of unsaturation present in compound (A + B + C) is ?

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  9. Within each set, which compound should be more reactive toward carbony...

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  10. Match the Column (I) and Column (II). (Matrix)

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  11. Consider reactions A through F. Those carbon atoms undergoing change, ...

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  12. Consider the possible formation of an aldehyde or ketone product when ...

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  13. Wittig reaction : The reaction of a phosphorus ylide with an aldehyd...

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  14. Wittig reaction : The reaction of a phosphorus ylide with an aldehyd...

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  15. Wittig reaction : The reaction of a phosphorus ylide with an aldehyd...

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  16. Wittig reaction : The reaction of a phosphorus ylide with an aldehyd...

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  17. Wittig reaction : The reaction of a phosphorus ylide with an aldehyd...

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  18. Wittig reaction : The reaction of a phosphorus ylide with an aldehyd...

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  19. Match the column :

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  20. Reactant (A) is :

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  21. Product (B) is :

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