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Given are cyclohexanol (I), acetic acid ...

Given are cyclohexanol (I), acetic acid (II) 2,4,6-trinitrophenol (III) and phenol (IV). In these the order of decreasing acidic character will be :

A

`IIgtIIIgtIVgtI`

B

`IIIgtIVgtIIgtI`

C

`IIIgtIIgtIVgtI`

D

`IIIgtIIgtIgtIV`

Text Solution

Verified by Experts

The correct Answer is:
C

Phenols and carboxylic acids are more acidic than aliphatic alcohols , therefore , cyclohehexanol (I) is least acidic . Out of two phenols . III is more acidic than IV because of the presence of three electron withdrawing `-NO_(2)` groups on the benzence ring which make O-H bond as highly polarized .Acetic acid (II) is more acidic than phenols and cyclohexanol but less acidic than trinitrophenol. Therefore , correct order is :
`IIIgtIIgtIVgtI`.
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