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With reference to the chemical reaction ...

With reference to the chemical reaction
`K_2 Cr_2O_7 + 14HCl to 2KCl + 2CrCl_3 + 3Cl_2 + ` Consider the following statements
1. `K_2Cr_2O_7` acts as oxidising agent.
2. HCl is the reducing agent.
3. `K_2Cr_2O_7` is the reducing agent.
4. HCl is the oxidising agent.
Which of the following statements are correct?

A

1 and 2

B

2 and 3

C

1 and 4

D

2 and 4

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the given chemical reaction and determine the correctness of the statements, we will follow these steps: ### Step 1: Identify the Reactants and Products The reaction given is: \[ K_2Cr_2O_7 + 14HCl \rightarrow 2KCl + 2CrCl_3 + 3Cl_2 + 7H_2O \] ### Step 2: Determine Oxidation States - **Potassium Dichromate (\(K_2Cr_2O_7\))**: - The oxidation state of chromium (Cr) in \(K_2Cr_2O_7\) is +6. - **Chromium Chloride (\(CrCl_3\))**: - The oxidation state of chromium (Cr) in \(CrCl_3\) is +3. ### Step 3: Analyze Changes in Oxidation States - The change in oxidation state for chromium is from +6 in \(K_2Cr_2O_7\) to +3 in \(CrCl_3\). This indicates that chromium is being reduced (gaining electrons). - Since \(K_2Cr_2O_7\) is causing the reduction of chromium, it is acting as an oxidizing agent. ### Step 4: Identify the Role of HCl - In this reaction, hydrochloric acid (HCl) provides chloride ions (Cl⁻) which are oxidized to chlorine gas (Cl₂). - Thus, HCl is losing electrons and is acting as a reducing agent. ### Step 5: Evaluate the Statements 1. **\(K_2Cr_2O_7\) acts as an oxidizing agent.** - **Correct** (as it is reduced). 2. **HCl is the reducing agent.** - **Correct** (as it is oxidized). 3. **\(K_2Cr_2O_7\) is the reducing agent.** - **Incorrect** (it is the oxidizing agent). 4. **HCl is the oxidizing agent.** - **Incorrect** (it is the reducing agent). ### Conclusion The correct statements are: - Statement 1: Correct - Statement 2: Correct - Statement 3: Incorrect - Statement 4: Incorrect ### Final Answer The correct statements are 1 and 2. ---

To analyze the given chemical reaction and determine the correctness of the statements, we will follow these steps: ### Step 1: Identify the Reactants and Products The reaction given is: \[ K_2Cr_2O_7 + 14HCl \rightarrow 2KCl + 2CrCl_3 + 3Cl_2 + 7H_2O \] ### Step 2: Determine Oxidation States - **Potassium Dichromate (\(K_2Cr_2O_7\))**: ...
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