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If the concentration of OH^(-) ions in t...

If the concentration of `OH^(-)` ions in the reaction
`Fe(OH)_(3)(s)hArrFe^(+3)(aq)+3OH^(-)(aq)`
is decreased by `1/4` times, then the equilibrium concentration of `Fe^(+3)` ions will increase by :

A

8 times

B

16 times

C

64 times

D

4 times

Text Solution

Verified by Experts

The correct Answer is:
C

`K=([Fe^(+3)][OH^(-)]^(3))/([Fe(OH)_(3)](s))`
= `[Fe^(+3)][OH^(-)]^(3)`
= `xy^(3)(aq)`
If `[OH^(-)]` is decreased to `y/4`, to keep K constant, `x.(y/4)^(3)=xy^(3)orx.=64x`
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