Home
Class 12
CHEMISTRY
For M^(+2)//M and M^(+3)//M^(+2) systems...

For `M^(+2)//M` and `M^(+3)//M^(+2)` systems, the `E^(@)` values for some metals are as follows :
`Cr^(+2)//Cr=-0.9V, Cr^(+3)//Cr^(+2)=-0.4V`
`Mn^(+2)//Mn=-1.2V, Mn^(+3)//Mn^(+2)=+1.5V`
`Fe^(+2)//Fe=-0.4V, Fe^(+3)//Fe^(+2)=+0.80V`
Use this data to comment upon :
the stability of `Fe^(+3)` in acid solution as compared to `Cr^(+3)` or `Mn^(+3)`

Text Solution

Verified by Experts

Higher the reduction potential of species, greater is the tendency for its reduction to take place. Therefore, `Mn^(+3)`, with the highest reduction potential would be readily reduced to `Mn^(+2) (Mn^(+3)+e to Mn^(+2))` and hence is least stable. Thus, from the values of reductions potential, it is clear that the stability of `Fe^(+3)` in acidic solution is more than `Mn^(+3)`, but less than that of `Cr^(+3)`.
Promotional Banner

Topper's Solved these Questions

  • TRANSITION AND INNER TRANSITION ELEMENTS

    PREMIERS PUBLISHERS|Exercise OTHER IMPORTANT QUESTIONS & ANSWERS (I. Choose the correct answer)|27 Videos
  • SURFACE CHEMISTRY

    PREMIERS PUBLISHERS|Exercise OTHER IMPORTANT QUESTIONS & ANSWERS (II. Answer the following questions:)|57 Videos
PREMIERS PUBLISHERS-TRANSITION AND INNER TRANSITION ELEMENTS -OTHER IMPORTANT QUESTIONS & ANSWERS (II. Answer the following questions)
  1. Name the oxometal anoins of the first series of the transition metals ...

    Text Solution

    |

  2. What are the stable oxidation states of the transition elements with t...

    Text Solution

    |

  3. For M^(+2)//M and M^(+3)//M^(+2) systems, the E^(@) values for some me...

    Text Solution

    |

  4. For M^(+2)//M and M^(+3)//M^(+2) systems, the E^(@) values for some me...

    Text Solution

    |

  5. How is the variability of oxidation states of transition metals differ...

    Text Solution

    |

  6. How would you account for the following ? Many of the transition el...

    Text Solution

    |

  7. How would you account for the following ? The metallic radii of the...

    Text Solution

    |

  8. How would you account for the following ? There is a greater range ...

    Text Solution

    |

  9. Calculate the number of unpaired electrons in the following gaseous io...

    Text Solution

    |

  10. The electronic configuration of chromium and copper are [Ar]3d^(5)4s^(...

    Text Solution

    |

  11. The melting and boiling points of Zn, Cd and Hg are low why ?

    Text Solution

    |

  12. Why Zn, Cd and Hg are soft and have low melting point ?

    Text Solution

    |

  13. Account for the trend in melting points of 3d series.

    Text Solution

    |

  14. Explain why manganese has a lower melting point than chromium.

    Text Solution

    |

  15. The second and third members of each group of transition elements have...

    Text Solution

    |

  16. The atomic radii of the elements in a transition series do not vary mu...

    Text Solution

    |

  17. How would you account for the following ? The atomic radius of meta...

    Text Solution

    |

  18. How would you account for the following ? Chromium is a typical ha...

    Text Solution

    |

  19. How would you account for irregular variation of ionisation enthalpies...

    Text Solution

    |

  20. Silver atom has completely 'd' orbitals (4d^(10)) in its ground state....

    Text Solution

    |