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For the following three reaction (i), (i...

For the following three reaction (i), (ii) and (iii) equilibrium constants are given
(i) `CO_((g)) +H_(2)O_((g)) hArr CO_(2(g)) +H_(2(g)) K_(1)`
(ii) `CH_(4(g)) +H_(2)O_((g)) hArr CO_((g)) +3H_(2(g)) K_(2)`
(iii) `CH_(4(g)) +2H_(2)O_((g)) hArr CO_(2(g)) +4H_(2(g)) K_(3)`
Which of the following relation is correct ?

A

`K_(3)*K_(2)^(3) = K_(1)^(2)`

B

`K_(2)*K_(3)=K_(1)`

C

`K_(1) sqrt(K_(2)) =K_(3)`

D

`K_(3)=K_(1)K_(2)`

Text Solution

Verified by Experts

The correct Answer is:
D

Add (i) & (ii) `rArr` gives
Reaction (iii)
`:.K_(1)K_(2)=K_(3)`
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