Cumulene With Even No. Of π Bonds|Cumulene With Odd No. Of π Bonds|Case Of Spiranes (Spiranes With Even Rings)|Spiranes With Odd Rings|Case Of Cycloalkylidene|Case Of Ortho-Ortho-Tetra Substituted Biphenyls|Summary

Stabilities of alkanes can be compared by converting these compounds to a common product and comparing the amount of the heat given off. One possiblitiy would be to measure the heat of combustion from converting alkenes to xo_(2) and H_(2)O . The heats of combustion are of large values and measuring small difference in these large numbers is difficult. Alkene of the lowest heat of combustion among isomeric alkenes is of the lowest energy and is most stable. Th stability of alkenes is often compared by meansuring the ehat of hydrogenation 9 heat given off, Delta H_(h)^(@) during catalytic hydrogenation. The heat of hydrogenation is in smal number, which provides more accurate energy difference. For a compound containing more than one double bond, Delta_(h)^(@) is the sum of heat of hydrogenation of individual double bonds. For non - conjugated diens, this additive relatioship is found to hold. For conjugated dienes, however, the measured value is slightly lower than expected. Cumulated dienes, which are even less stable than non - conjugated dienes. The more stable is the alkene, lower is the heat of combustion and heat of hydrogenation. More highly substituted double bonds are usually more stable. In case of cyclokanes, compounds having higher angle strin are less stable. In which of the following is Delta H^_(h)^(@) the maximum ?

Stabilities of alkanes can be compared by converting these compounds to a common product and comparing the amount of the heat given off. One possiblitiy would be to measure the heat of combustion from converting alkenes to xo_(2) and H_(2)O . The heats of combustion are of large values and measuring small difference in these large numbers is difficult. Alkene of the lowest heat of combustion among isomeric alkenes is of the lowest energy and is most stable. Th stability of alkenes is often compared by meansuring the ehat of hydrogenation 9 heat given off, Delta H_(h)^(@) during catalytic hydrogenation. The heat of hydrogenation is in smal number, which provides more accurate energy difference. For a compound containing more than one double bond, Delta_(h)^(@) is the sum of heat of hydrogenation of individual double bonds. For non - conjugated diens, this additive relatioship is found to hold. For conjugated dienes, however, the measured value is slightly lower than expected. Cumulated dienes, which are even less stable than non - conjugated dienes. The more stable is the alkene, lower is the heat of combustion and heat of hydrogenation. More highly substituted double bonds are usually more stable. In case of cyclokanes, compounds having higher angle strin are less stable. Which statement is false ?

Stabilities of alkanes can be compared by converting these compounds to a common product and comparing the amount of the heat given off. One possiblitiy would be to measure the heat of combustion from converting alkenes to xo_(2) and H_(2)O . The heats of combustion are of large values and measuring small difference in these large numbers is difficult. Alkene of the lowest heat of combustion among isomeric alkenes is of the lowest energy and is most stable. Th stability of alkenes is often compared by meansuring the ehat of hydrogenation 9 heat given off, Delta H_(h)^(@) during catalytic hydrogenation. The heat of hydrogenation is in smal number, which provides more accurate energy difference. For a compound containing more than one double bond, Delta_(h)^(@) is the sum of heat of hydrogenation of individual double bonds. For non - conjugated diens, this additive relatioship is found to hold. For conjugated dienes, however, the measured value is slightly lower than expected. Cumulated dienes, which are even less stable than non - conjugated dienes. The more stable is the alkene, lower is the heat of combustion and heat of hydrogenation. More highly substituted double bonds are usually more stable. In case of cyclokanes, compounds having higher angle strin are less stable. If the heat of hydrogenation of cyclooctene is about 23 k cal mo^(-1) , what would be the probable DeltaH_(b) or 1,3,5,7- cyclooctatetraene ?

Stabilities of alkanes can be compared by converting these compounds to a common product and comparing the amount of the heat given off. One possiblitiy would be to measure the heat of combustion from converting alkenes to xo_(2) and H_(2)O . The heats of combustion are of large values and measuring small difference in these large numbers is difficult. Alkene of the lowest heat of combustion among isomeric alkenes is of the lowest energy and is most stable. Th stability of alkenes is often compared by meansuring the ehat of hydrogenation 9 heat given off, Delta H_(h)^(@) during catalytic hydrogenation. The heat of hydrogenation is in smal number, which provides more accurate energy difference. For a compound containing more than one double bond, Delta_(h)^(@) is the sum of heat of hydrogenation of individual double bonds. For non - conjugated diens, this additive relatioship is found to hold. For conjugated dienes, however, the measured value is slightly lower than expected. Cumulated dienes, which are even less stable than non - conjugated dienes. The more stable is the alkene, lower is the heat of combustion and heat of hydrogenation. More highly substituted double bonds are usually more stable. In case of cyclokanes, compounds having higher angle strin are less stable. The wrong option among the following statements is :

Stabilities of alkanes can be compared by converting these compounds to a common product and comparing the amount of the heat given off. One possiblitiy would be to measure the heat of combustion from converting alkenes to xo_(2) and H_(2)O . The heats of combustion are of large values and measuring small difference in these large numbers is difficult. Alkene of the lowest heat of combustion among isomeric alkenes is of the lowest energy and is most stable. Th stability of alkenes is often compared by meansuring the ehat of hydrogenation 9 heat given off, Delta H_(h)^(@) during catalytic hydrogenation. The heat of hydrogenation is in smal number, which provides more accurate energy difference. For a compound containing more than one double bond, Delta_(h)^(@) is the sum of heat of hydrogenation of individual double bonds. For non - conjugated diens, this additive relatioship is found to hold. For conjugated dienes, however, the measured value is slightly lower than expected. Cumulated dienes, which are even less stable than non - conjugated dienes. The more stable is the alkene, lower is the heat of combustion and heat of hydrogenation. More highly substituted double bonds are usually more stable. In case of cyclokanes, compounds having higher angle strin are less stable. Arrange the following compounds according to their increasing heat of combustion. I. 1- Butene II. ci -2- Butene III. trans -2- Butene IV. 2- Methyl propene

A note book is made up of sheets folded in the middle and stapled. Each sheet form two leaves i.e., four pages. On removing some papers of the first half and second half of the book, Joe found the number of the leaves, in the first case as odd and in the second case as even. If the sum of the numbers of the pages on the last leaf of the book is 63, then what could be the maximum possible sum of the numbers on the pages of leaves that were left in the book.

Median of a distribution is the value of the variable which divides it into equal parts . In case of individual observations x_1,x_2 .. x_n , if the number of observations is odd, then median is the value of ((n+1)/2) th observation when the observations have been arranged in ascending or descending order of magnitude. In case of even number of observations median is the A.M. of the values of (n/2) th and (n/2+1) th observations, arranged in ascending or descending order of magnitude . The mode of distribution is that value of the variable for which the frequency is maximum . Median of the distribution 8,5,7,9,13,11,20,23 , 25 ,28 , 27 is

Median of a distribution is the value of the variable which divides it into equal parts . In case of individual observations x_1,x_2 .. x_n , if the number of observations is odd, then median is the value of ((n+1)/2) th observation when the observations have been arranged in ascending or descending order of magnitude. In case of even number of observations median is the A.M. of the values of (n/2) th and (n/2+1) th observations, arranged in ascending or descending order of magnitude . The mode of distribution is that value of the variable for which the frequency is maximum . Median of the distribution 25,20,11,3,12,18,17 ,9,21,22 is

Median of a distribution is the value of the variable which divides it into equal parts . In case of individual observations x_1,x_2 .. x_n , if the number of observations is odd, then median is the value of ((n+1)/2) th observation when the observations have been arranged in ascending or descending order of magnitude. In case of even number of observations median is the A.M. of the values of (n/2) th and (n/2+1) th observations, arranged in ascending or descending order of magnitude . The mode of distribution is that value of the variable for which the frequency is maximum . The mode of following series is {:("value (x)",40,44,48,52,56,62,64,72,76),("frequency (f)",10,12,14,20,15,19,18,8,4):}