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Calculate the lattice energy of CaCl(2) ...

Calculate the lattice energy of `CaCl_(2)` from the given data
`Ca(s) +Cl_(2)(g) rarr CaCl_(2)(s) Delta H_(f)^(0) =-795" kJ mol"^(-1)`
`{:("Atomisation ": Ca(s) rarr Ca(g)" "Delta_(1)^(0)=+121" kJ mol"^(-1)),("Ionisation ": Ca(g) to Ca^(2+)(g) +2e^(-)" "Delta H_(2)^(0) =+2422" kJ mol"^(-1)), ("Dissociation ": Cl_(2)(g) to 2Cl(g)" "Delta H_(3)^(0) =+242.8" kJ mol"^(-1)),("Electron affinity": Cl(g) +e^(-) to Cl^(-)(g)" "Delta H_(4)^(0)=-355" kJ mol"^(-1)):}`

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Verified by Experts


`Delta H_(f) = Delta H_(1) + Delta H_(2) + Delta H_(3)+ 2 Delta H_(4) + u`
`-795 =121+2422+242.8+(2xx-355) +u`
`-795=2785.8-710 +u`
`-795= 2075.8 +u`
`u =-795-2075.8`
`u = -2870.8" kJ mol"^(-1)`
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Calculate the lattice energy of CaCl_2 from the given data. Ca_((s)) + Cl_(2(g)) to CaCl_(2(s)) DeltaH_f^0 =-795 "kJ mol"^(-1) Sublimation : Ca_((s)) to Ca_((g)) " " DeltaH_1^0=+121 "kJ mol"^(-1) Ionisation : Ca_((g)) to Ca_((g))^(2+) +2e^(-) " " DeltaH_2^0=+2422 "kJ mol"^(-1) Dissociation : Cl_(2(g)) to 2Cl_((g)) " " DeltaH_3^0=+242.8 "kJ mol"^(-1) Electron affinity : Cl_((g)) + e^(-) to Cl_((g))^(-) " " DeltaH_4^0=-355 "kJ mol"^(-1)

Calculate the lattice energy of formation of NaCl from the following data : Na_((s)) +1//2Cl_(2(g)) to NaCl_((s)) Delta H_(f) -411.3 KJ.mol^(-1) Heat of sublimation of Na_((s)) = 108 . 7 kJ mol ^(-1) Ionisation energy of Na_((g)) = 49.5.0 kJ mol^(-1) Dissociation energy of Cl_(2(g)) = 244 kJ mol^(-1) Electron affinity of Cl_((g)) = - 349 . 0 kJ mol^(-1)

Calculate the standard enthalpy of formation of CH_3OH_((l)) from the following data : (i) CH_3OH_((l)) +3//2 O_(2(g)) to CO_(2(g)) + 2H_2O_((l)) , Delta_r H^(Ө)=-726 "kJ mol"^(-1) (ii) C_((s)) + O_(2(g)) to CO_(2(g)) , Delta_c H^(Ө)=-393 "kJ mol"^(-1) (iii) H_(2(g)) +1//2O_(2(g)) to H_2O_((l)) , Delta_f H^(Ө)=-286 "kJ mol"^(-1)

Calculate the lattice enthalpy of CaCl_(2) given that the enthalpy of : i) Sublimation of Ca in "121.8 kJ mol"^(-1) ii) Dissociation of Cl_(2) to 2Cl is "242.8 kJ mol"^(-1) iii) Ionisation of Ca" to "Ca^(2+)" is 2422 kJ mol"^(-1) iv) Electron gain for Cl" to "Cl^(-)" is - 355 kJ mol"^(-1) v) DeltaH_(f)^((o))" overall is "-"795 kJ mol"^(-1)

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