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In context with the transition elements,...

In context with the transition elements, which of the following statements is incorrect?

A

In addition to the normal oxidation state, the zero oxidation state is also shown by these elements in complexes.

B

In the highest oxidation state, the transition metal shows basic character of its oxide, and form the cationic complexes.

C

In the highest oxidation state of the first five transition elements (Sc to Mn), all the 4s and 4d electrons are used for bonding.

D

Once the `d^(5)` configuration is exceeded, the tendency to involve all the 3d electrons in bonding decreases.

Text Solution

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The correct Answer is:
B

As the oxidation state increases, the electronegativity increases. Thus, the acidic characteristic increases. So, basic characteristic greater is lower oxidation state and acidic character predominates with the increase in oxidation state.
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NTA MOCK TESTS-THE D-AND F-BLOCK ELEMENTS TEST-SINGLE CHOICE
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  2. A green coloured solution of a salt, changes its colour to light pink ...

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  3. Which one of the following transition metal ions is diamagnetic?

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  4. Which of the following pair of transition metal ions have the same cal...

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  5. Which of the following is coloured compound?

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  6. In context with the transition elements, which of the following statem...

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  7. In the context of the lanthanides, which of the following statements i...

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  8. The transition elements are more metallic than the representative elem...

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  9. The Potassium manganate (K(2) MnO(4)) is formed, when

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  10. The calculated value of magnetic moment of Fe^(3+) is

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  11. The pair in which both species have same magnetic moment is -

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  12. Cr^(2+) and Mn^(3+) both have d^(4) configuration. Thus

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  13. Match the catalysts to the correct process.

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  14. Which of the following statements is/are false?

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  15. Which statements among the following are correct? I. Ce^(+4) is an...

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  16. On heating Pyrolusite with KOH in the presence of air, we get

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  17. The lanthanide contraction is responsible for the fact that

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  18. Regarding transitional elements, the wrong statement is

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  19. A very slight decrease in atomic radius occurs in a transition series ...

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  20. Which of the following does not represent the correct order of the pro...

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