Home
Class 12
CHEMISTRY
A catalyst lowered the activation energy...

A catalyst lowered the activation energy by `25 kJ mol^(-1)` at `25^(@)C`. By how many times will the rate grow?

A

14069

B

24069

C

16049

D

19049

Text Solution

Verified by Experts

The correct Answer is:
B

The rate of reaction is related to the activation energy by the following relation:
Given `triangleE=25 xx10^(3) j ,R =8.314 j k^(-1) mol^(-1)`
substituting all the values in Eq (i) get `(k_(2))/(k_(1))` = Antilog `[(25xx10E^(3))/(2.303xx8.314 xx298)]` =24069
`therefore k_(2) =k_(1) xx24069` Therefore the rate increased by 24069 times
Promotional Banner

Similar Questions

Explore conceptually related problems

A catalyst lowers the activation energy from 20 kJ mol^(-1) to 15 kJ mol^(-1) of the forward direction of the reaction A rarr B which of the following statement regarding the reaction is correct

A catalyst lowers the activation energy of the forward reaction by 10 kJ "mol"^(-1) ,What effect it has on the activation energy of the backward reaction?

In presence of a catalyst, the activation energy is lowered by 3 kcal at 27^@C . Hence, the rate of reaction will increase by:

An endothermic reaction A to B has an activation energy of 15" kJ mol"^(-1) and the enthalpy change for the reaction is 5" kJ mol"^(-1) . The activation energy of the reaction B to A is

The activation energy of a reaction is 24.0 kcal mol^(-1) at 27^(@)C and the presence of catalyst changes its activation energy to one-fourth at the same temperature. The approximate ratio of rate in the presence of catalyst to rate in the absence of catalyst will be (use R = 2 cal mol^(-1) K^(-1) ).

The energy of activation for a reaction is 100 (kJ) mol^(-1) . Presence of a catalyst lowers the energy of activation by 75 %. What will be the effect on the rate of reaction at (20^oC) , other things being equal.